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What is the minimum volume of water required to dissolve `1.0 g` of calcium sulphate at `298 K`?
(For calcium sulphate , `K_(sp) is 9.1xx10^(-6))`.

Text Solution

Verified by Experts

`CaSO_(4)(s)hArrCa^(2+) (aq) + SO_(4)^(2-) (aq)`
If s is the solubility of `CaSO_(4)` in moles `L^(-1)`, then `K_(sp)=[Ca^(2+)]xx[SO_(4)^(2-)]=s^(2)`
or `s=sqrt(K_(sp))=sqrt(9.1xx10^(-6))=3.02xx10^(-3) "mol" L^(-1) = 3.02xx10^(-3) xx 136 g L^(-1) = 0.411 g L^(-1)` [Molar mass of `CaSO_(4) = 136 g "mol"^(-1)`)
Thus, for dissolving 0.411 g, water required = 1 L
`:. ` For dissolving 1 g, water required `=(1)/(0.411) L = 2.43 L`.
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