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How many times a 0.1 M strong monobasic ...

How many times a 0.1 M strong monobasic solution should be diluted so that the pH of the resulting solution is tripled ?

A

20 times

B

200 times

C

`5.55 xx 10^(2)` times

D

`5.55xx10^(4) ` times

Text Solution

Verified by Experts

The correct Answer is:
D

pH of a weak acid `=(1)/(2)[pK_(a)-log c]`
`:.x=(1)/(2) [ pK_(a)-log 1] = (1)/(2) pK_(a)`
and `2x=(1)/(2)[pK_(a)-log c]`
or `pK_(a)=(1)/(2) pK_(a)-(1)/(2)log c (.:' 2x=pK_(a)]`
or `(1)/(2) log c = - (1)/(2) pK_(a)`
or `log c = -pK_(a)=log K_(a)`
or `c=K_(a)=1.8xx10^(-5)`
`:.` Dilution `=(1)/(1.8xx10^(-5))=5.55xx10^(4)` times
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