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When solid lead iodide is added to water...

When solid lead iodide is added to water, the equilibrium concentration of `I^(-)` becomes `2.6 xx 10^(-3)M` . What is the `K_(sp)` for `PbI_(2)` ?

A

`2.2xx10^(-9)`

B

`8.8xx10^(-9)`

C

`1.8xx10^(-8)`

D

`3.5xx10^(-8)`

Text Solution

Verified by Experts

The correct Answer is:
B

`PbI_(2)hArrPb^(2+)+2I^(-)`
Thus, `Pb^(2+)` ion concentration is half of the `I^(-)` ion concentration
`[I^(-)]=2.6xx10^(-3)M :.[Pb^(2+)]=1.3xx10^(-3)M`
`K_(sp)=[Pb^(2+)][I^(-)]^(2)`
`=(1.3xx10^(-3)) (2.6xx10^(-3))^(2)=8.8xx10^(-9)`.
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