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Complete the following reactions : (i)...

Complete the following reactions :
(i) `P_(4) + SOCl_(2) rarr`
(ii) `CH_(3)COOH + PCl_(5) rarr`

Text Solution

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(i) White phosphorus `(P_(4))` reacts with thionyl chloride `(SOCl_(2))` to form phosphorus trichloride `(PCl_(3))`
`P_(4)+8SOCl_(2)to4PCl_(2)+4SO_(4)+2S_(2)Cl_(2)`
(ii) Acetic acid reacts with phosphorus pentachloride `(PCl_(5))` to form acetly chloride
`underset("Acetic acid")(CH_(3)COOH)+PCl_(5)tounderset("Acetyl chloride")(CH_(3)COCl)+POCl_(3)+HCl`
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  10. Why is PCl(5) more covalent than PCl(3) ?

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  11. Why does PCl(5) fume in moisture ?

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  14. What is the oxidation number of phosphorus in H(3)PO(2) molecule ?

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  15. H(3)PO(2)andH(3)PO(3) act as good reducing agents but H(3)PO(4) does n...

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  16. Why does H(3)PO(3) act as a reducing agent but H(3)PO(4) does not ?

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  17. Why does orthophosphoric acid exist as a syrupy liquid ?

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  18. How is pyrophosphoric acid related to orthophosphoric acid ?

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  19. What kind of molecules show disproportionation reactions ? Give one e...

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  20. CN^(-) ion is known but CP^(-) ion is not known.

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