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The conductivity of a solution of AgCl a...

The conductivity of a solution of AgCl at 298 K is found to be `1.382xx10^(-6)Omega^(-1)cm^(-1)` the ionic conductance of `Ag^(+)` and `Cl^(-)` at infinite dilution are `61.9Omega^(-1)cm^(2)col^(-1)` ad `76.3Omega^(-1)cm^(2)mol^(-1)` respectively the solubility of AgCl is

Text Solution

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`wedge_(m)^(@)(AgCl)=lamda_(ag^(+))^(@)+lamda_(Cl^(-))^(@)=61.9+76.3=138.2" S "cm^(2)mol^(-1)`
Solubility `=(kappaxx1000)/(wedge_(m)^(@))=(1.382xx10^(-6)xx1000)/(138.2)=10^(-5)" mol "L^(-1)=10^(-5)xx143.5" g "L^(-1)=1.435xx10^(-3)g" "L^(-1)`.
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