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Find out the molar conductivity of an aq...

Find out the molar conductivity of an aqueous solution of `BaCl_(2)` at infinite dilution when ionic conductances of `Ba^(2+)` and `Cl^(-)` ion are 127.30 S `cm^(2)mol^(-1)` and 76.34 S `cm^(2)mol^(-1)` respectively.

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To find the molar conductivity of an aqueous solution of \( \text{BaCl}_2 \) at infinite dilution, we can use the following formula: \[ \Lambda^0_m = \Lambda^0_{Ba^{2+}} + 2 \Lambda^0_{Cl^-} \] Where: - \( \Lambda^0_m \) is the molar conductivity of \( \text{BaCl}_2 \) at infinite dilution. - \( \Lambda^0_{Ba^{2+}} \) is the ionic conductivity of the \( \text{Ba}^{2+} \) ion. - \( \Lambda^0_{Cl^-} \) is the ionic conductivity of the \( \text{Cl}^- \) ion. ### Step-by-step Solution: 1. **Identify the given values:** - Ionic conductance of \( \text{Ba}^{2+} \): \( \Lambda^0_{Ba^{2+}} = 127.30 \, \text{S cm}^2 \text{mol}^{-1} \) - Ionic conductance of \( \text{Cl}^- \): \( \Lambda^0_{Cl^-} = 76.34 \, \text{S cm}^2 \text{mol}^{-1} \) 2. **Write the formula for molar conductivity of \( \text{BaCl}_2 \):** \[ \Lambda^0_m = \Lambda^0_{Ba^{2+}} + 2 \Lambda^0_{Cl^-} \] 3. **Substitute the known values into the formula:** \[ \Lambda^0_m = 127.30 + 2 \times 76.34 \] 4. **Calculate the contribution from \( \text{Cl}^- \):** \[ 2 \times 76.34 = 152.68 \] 5. **Add the contributions together:** \[ \Lambda^0_m = 127.30 + 152.68 = 279.98 \, \text{S cm}^2 \text{mol}^{-1} \] 6. **Final result:** \[ \Lambda^0_m \approx 279.99 \, \text{S cm}^2 \text{mol}^{-1} \] ### Conclusion: The molar conductivity of an aqueous solution of \( \text{BaCl}_2 \) at infinite dilution is approximately \( 279.99 \, \text{S cm}^2 \text{mol}^{-1} \).

To find the molar conductivity of an aqueous solution of \( \text{BaCl}_2 \) at infinite dilution, we can use the following formula: \[ \Lambda^0_m = \Lambda^0_{Ba^{2+}} + 2 \Lambda^0_{Cl^-} \] Where: - \( \Lambda^0_m \) is the molar conductivity of \( \text{BaCl}_2 \) at infinite dilution. ...
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