Home
Class 12
CHEMISTRY
The measured e.m.f. at 25^(@)C for the c...

The measured e.m.f. at `25^(@)C` for the cell reaction ,
`Zn(S)+Cu^(2+)(1.0 M)to Cu(s) +Zn^(2+) (0.1 M)` is 1.3 volt, Calculate `E^(@)` for the cell reaction.

Text Solution

Verified by Experts

The correct Answer is:
`1.27045V`

`E_(cell)=E_(cell)^(@)-(0.0591)/(n)"log"([Zn^(2+)])/([Cu^(2+)]),1.3=E_(cell)^(@)-(0.0591)/(2)"log"(0.1)/(0.1)" or "E_(cell)^(@)=1.27045V`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    PRADEEP|Exercise Advanced Problem For Competitions|17 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise TEST YOUR GRIP (MUTIPLE CHOICE QUESTION)|20 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise Curiosity Question|5 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS|30 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    PRADEEP|Exercise Curiosity Questions|2 Videos

Similar Questions

Explore conceptually related problems

The measured e.m.f. at 25^(@)C for the cell reaction, Zn(s) +XCu^(2+)._((eq))(1.0M) rarr Cu(s) ._((aq))(0.1M) is 1.3 volt, calculate E^(@) for the cell reaction.

The standard emf for the cell cell reaction Zn + Cu^(2+) rarr Zn^(2+) + Cu is 1.10 volt at 25^@ C . The emf for the cell reaction when 0.1 M Cu^(2+) and 0.1 M ZN^(2+) solutions are used at 25^@ =C is .

The standard emf for the cell reaction, Zn+Cu^(2+) to Cu^(2+) to Cu+Zn^(2+)," is "1.1V" at "25^(@)C." If 0.1 M "Cu^(2+) and 0.1M Zn^(2+) solutions are used then

E^(@) for the cell Zn(s)|Zn^(2+)(aq)|Cu^(2+)(aq)|Cu(s) is 1.1V at 25^(@)C the equilibrium constant for the cell reaction is about

E^(@) for the electrochemical cell Zn(s)|Zn^(2+) 1 M (Aq.)||Cu^(2+) 1 M (aq.)|Cu(s) is 1.10 V at 25^(@)C . The equilibrium constant for the cell reaction, Zn(s) +Cu^(2+) (aq.) hArr Zn^(2+) (aq.)+Cu(s) Will be :

PRADEEP-ELECTROCHEMISTRY-Problem for Practice
  1. Calculate the standard electrode potential of Ni^(2+)/Ni electrode if ...

    Text Solution

    |

  2. A voltaic cell is set up at 25^(@)Cwith the following half cells : A...

    Text Solution

    |

  3. The measured e.m.f. at 25^(@)C for the cell reaction , Zn(S)+Cu^(2+)...

    Text Solution

    |

  4. Calculate the potential of the following cell reaction at 298 K Sn^(...

    Text Solution

    |

  5. Calculate the potential of a zinc-zinc ion electrode in which the zinc...

    Text Solution

    |

  6. (a) Calculate the electrode potential of silver electrode dipped in 0....

    Text Solution

    |

  7. Cu^(2+)+2e^(-)toCu,E^(@)=+0.34V,Ag^(+)+1e^(-)toAg,E^(@)=+0.80V (i) C...

    Text Solution

    |

  8. Calculate the potential for half cell containing 0.10 M K(2)Cr(2)O(7)(...

    Text Solution

    |

  9. Calculate the emf of the following cell at 298K: Fe(s)|Fe^(2+)(0.001...

    Text Solution

    |

  10. Calculate emf of the following cell at 25^(@)C: Fe|Fe^(2+)(0.001m)||...

    Text Solution

    |

  11. Calculate the e.m.f. of the following cell at 298K: 2Cr(s)+3Fe^(2+)(...

    Text Solution

    |

  12. Calculate the equilibrium cosntant for the reaction, Zn+Cd^(2+)hArrZn^...

    Text Solution

    |

  13. Calculate the equilibrium constant for the reaction at 298K. Zn(s) +...

    Text Solution

    |

  14. Calculate the equilibrium constant for the cell reaction : 4Br^(-)+O...

    Text Solution

    |

  15. Calculate the equilibrium constant for the reaction, 2Fe^(3+)+3I^(-)hA...

    Text Solution

    |

  16. Calculate the equilibrium constant for the reaction at 298K: NiO(2)+...

    Text Solution

    |

  17. Calculate the equilibrium constant for the following reaction at 298K....

    Text Solution

    |

  18. For the cell reaction, Mg|Mg^(2+) (aq.)||Ag^(+) (aq.)|Ag calculate...

    Text Solution

    |

  19. For the reaction N(2)(g)+3H(2)(g)hArr2NH(3)(g) at 298K, enthalpy and e...

    Text Solution

    |

  20. Determine the values of equilibrium constant (K(c)) and DeltaG^(@) for...

    Text Solution

    |