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Which of the following statement is corr...

Which of the following statement is correct?

A

`E_(cell) and Delta_(r)G` of cell reaction both are extensive properties.

B

`E_(cell) and Delta_(r)G` of cell reaction both are intensive properties.

C

`E_(cell)` is an intensive properties while `Delta_(r)G` of cell reaction is an extensive property.

D

`E_(cell)` is an extensive property while `Delta_(r)G` of cell reaction is an intensive property.

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AI Generated Solution

The correct Answer is:
To determine which statement is correct regarding intensive and extensive properties, let's analyze the properties and the statements provided. ### Step-by-Step Solution: 1. **Understand Intensive and Extensive Properties**: - **Intensive Properties**: These properties do not depend on the amount of substance present. Examples include temperature, pressure, and density. - **Extensive Properties**: These properties depend on the amount of substance present. Examples include mass, volume, and total energy. 2. **Identify the Properties of Interest**: - In this question, we are particularly interested in the properties of E_cell (cell potential) and ΔG (Gibbs free energy). 3. **Analyze E_cell**: - E_cell is an intensive property. This means that the value of E_cell does not change regardless of the size or extent of the system. You cannot simply add E_cell values from different reactions to get a combined E_cell. 4. **Analyze ΔG**: - ΔG is an extensive property. This means that ΔG depends on the amount of substance involved in the reaction. You can add the ΔG values of two reactions to obtain the ΔG for the overall reaction. 5. **Conclusion**: - Based on the definitions and analysis, the correct statement is that E_cell is an intensive property and ΔG is an extensive property. Therefore, the correct option is the one that states this relationship. ### Final Answer: The correct statement is: E_cell is an intensive property, and ΔG is an extensive property.

To determine which statement is correct regarding intensive and extensive properties, let's analyze the properties and the statements provided. ### Step-by-Step Solution: 1. **Understand Intensive and Extensive Properties**: - **Intensive Properties**: These properties do not depend on the amount of substance present. Examples include temperature, pressure, and density. - **Extensive Properties**: These properties depend on the amount of substance present. Examples include mass, volume, and total energy. ...
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PRADEEP-ELECTROCHEMISTRY-NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTIONS (MULTIPLE QUESTIONS-I)
  1. Which cell will measure standard electrode potential of copper electro...

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  2. Electrode potential for Mg electrode varies according to the equation ...

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  3. Which of the following statement is correct?

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  4. The difference between the electrode potentials of two electrons when ...

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  5. Which of the following statement is not correct about an inert electro...

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  6. An electrochemical cell an behave like an electrolytic cell when

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  7. Which of the statements about solution of electrolytes is not correct?

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  8. Using the data given below: E(Cr(2)O(7)^(2-)|Cr^(3+))^(@)=1.33V E(Cl...

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  9. Find out which of the following is the strongest oxidizing agent.

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  10. Find out in which option the order of reducing power is correct.

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  11. Use the data given in Q.8 and find out the most stable ion in its redu...

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  12. Find out the most stable oxidised species.

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  13. The quantity of charge required to obtain one mole of aluminium from A...

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  14. The cell constant of a conductivity cell

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  15. While charging the lead storage battery:

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  16. wedge^(@)m[NH(4)OH] is equal to

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  17. In the electrolysis of aqueous sodium chloride solution which of the h...

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  18. Can absolute electrode potential of an electrode be measured?

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  19. Can E("cell")^(@) or Delta(r)G^(@) for cell reaction ever be equal to ...

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  20. Under what condition is E("cell")^(@)=0 or Delta(r)G=0?

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