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Using the data given below: E(Cr(2)O(7...

Using the data given below:
`E_(Cr_(2)O_(7)^(2-)|Cr^(3+))^(@)=1.33V E_(Cl_(2)|Cl^(-))^(@)=1.36V`
`E_(MnO_(4)^(-)|Mn^(2+))^(@)=1.51V E_(Cr^(3+)|Cr)=-0.74V`
Mark the strongest reducing agent.

A

`Cl^(-)`

B

`Cr`

C

`Cr^(3+)`

D

`Mn^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
C

Strongest reducing agent is one which is oxidized most easiliy, i.e., which has highest oxidation potential. Given values are reduction potentials. Reversing the sign will give oxidation potentials.thus, `Cr//Cr^(3+)` will have highest oxidation potential (+0.74V). hence, Cr is oxidized most easiliy `(CrtoCr^(3+)+3e^(-))` and, therefore, is the strongest reducing agent.
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Using the data given below: E_(Cr_(2)O_(7)^(2-)|Cr^(3+))^(@)=1.33V E_(Cl_(2)|Cl^(-))^(@)=1.36V E_(MnO_(4)^(-)|Mn^(2+))^(@)=1.51V E_(Cr^(3+)|Cr)=-0.74V Mark the strongest oxidising agent.

Using the data given below: E_(Cr_(2)O_(7)^(2-)|Cr^(3+))^(@)=1.33V E_(Cl_(2)|Cl^(-))^(@)=1.36V E_(MnO_(4)^(-)|Mn^(2+))^(@)=1.51V E_(Cr^(3+)|Cr)=-0.74V In which option the order of reducing power is correct?

Using the data given below: E_(Cr_(2)O_(7)^(2-)|Cr^(3+))^(@)=1.33V E_(Cl_(2)|Cl^(-))^(@)=1.36V E_(MnO_(4)^(-)|Mn^(2+))^(@)=1.51V E_(Cr^(3+)|Cr)=-0.74V Find the most stable ion in its reduced forms

Using the data given below: E_(Cr_(2)O_(7)^(2-)|Cr^(3+))^(@)=1.33V E_(Cl_(2)|Cl^(-))^(@)=1.36V E_(MnO_(4)^(-)|Mn^(2+))^(@)=1.51V E_(Cr^(3+)|Cr)=-0.74V Find the most stable oxidised species.

Using tha data given below is reducing potenial. E_(Cr_2O_7^(2-)//Cr^(3+))^@ =1.33 V , E_(Cl_2//Cl^-)^@ =1.36 V E_(MnO_4^(-)//Mn^(2+))^@ =1.51 V , E_(Cr^(3+) // Cr)^@ =- 0.74 V find out which of the following is the strongest oxidising agent.

PRADEEP-ELECTROCHEMISTRY-NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTIONS (MULTIPLE QUESTIONS-I)
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  5. Find out in which option the order of reducing power is correct.

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  7. Find out the most stable oxidised species.

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