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If the 0.05 molar solution of M^+ is rep...

If the 0.05 molar solution of `M^+` is replaced by a 0.0025 Molar `M^+` solution. then the magnitude of the cell potential would be :

A

35 mV

B

70 mV

C

140 mV

D

700 mV

Text Solution

Verified by Experts

The correct Answer is:
C

From the above equation,
`(2.303RT)/(F)"log(1)/(0.05)=70mV`
`=70xx10^(-3)V=0.07V`
`therefore(2.303RT)/(F)(1.301)=0.07`
or `(2.303RT)/(F)=(0.07)/(1.301)=0.0538`
For the new concentration,
`E_(cell)=(2.303RT)/(F)"log"(1)/(0.0025)`
`=0.0538log400=0.0538xx2.6021`
`=0.140V=140mV`
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