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Assertion (A): For a Daniell cell : Zn...

Assertion `(A):` For a Daniell cell `:`
`Zn|Zn^(2+)||Cu^(2+)|Cu` with `E_(cell)=1.1V`, the application of opposite potential greater than `1.1V` results into the flow of electron from cathod to anode. Reason `(R):` Zn is deposited at anode and Cu is dissolved at cathode

A

If both assertion and reason are true, and reason is the true explanation of the assertion

B

if both assertion and reason are true, but reason is not the true explanation of the assertion.

C

if assertion is true, but reason is false.

D

If both assertion and reason are false.

Text Solution

Verified by Experts

The correct Answer is:
B

Correct Explanation. On applyng external voltage greater than 1.1 V in the daniell cell, the electrons flow in the reverse direction, i.e., from cathode `(Cu^(2+)//Cu)` to anode `(Zn//Zn^(2+))`. The reverse reaction takes place
(i.e., `Zn^(2+)+CutoZn+Cu^(2+)`)
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