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When an organge crystalline compound (A)...

When an organge crystalline compound (A) was heated with common salt and concentrated sulphuric acid, an orange red gas (B) was evolved. Acidified solution of the comound (A) reacts with `H_(2)O_(2)` to produce a deep blue solution due to the formation of comopund (C ). The gas (B) on passing through NaOh solution gave a solution (D). The solution on reacting with an aqueous solution of lead acetate gave a yellow precipitate of (E).
Name the compounds A,B,C,D ( present in the soluiotn ) and E ( present as ppt.)

Text Solution

Verified by Experts

`underset("Potassium dichromate")underset((A)) (K_(2)Cr_(2)O_(7)) + 4NaCl + 6H_(2)SO_(4) rarr 2KHSO_(4) + 4NaHSO_(4) + underset( "Chromyl chloride")underset((B)) ( 2CrO_(2)Cl_(2))+3H_(2)O`
`K_(2)Cr_(2)O_(7) + H_(2)SO_(4) + 4H_(2)O_(2) rarr underset("Peroxo compound, " CrO(O_(2))_(2)) underset((B)) (2CrO_(5))+ K_(2)SO_(4) + 5H_(2)O`
`underset((B))(CrO_(2)Cl_(2)) +4NaOH rarr underset("Sodium chromate")underset((D)) (Na_(2)CrO_(4)) + 2NaCl+ 2H_(2)O`
`Na_(2) CrO_(4) + ( CH_(3) COO)_(2)Pb rarr underset("Lead chromate ( Yellow ppt.)")underset((E )) (PbCrO_(4)) + 2CH_(3) COONa`
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