Home
Class 12
CHEMISTRY
For the four successive transition eleme...

For the four successive transition elements (Cr, Mn, Fe, and Co), the stability of `+2` oxidation state will be there in which of the following order ?
`(At. Nos. Cr = 24, Mn = 25, Fe = 26, Co = 27)`

A

`Cr gt Mn gt Co gt Fe`

B

`Mn gtFe gt Cr gt Co`

C

`Fe gt Mn gt Co gt Cr`

D

`Co gt Mn gt Fegt Cr`

Text Solution

Verified by Experts

`Mn^(2+)(d^(5))` gets highest stabilization due to half filled configuration .In case of`Fe^(2+)(d^(6))` , addition of one extra electron in the subshell destabilizes it. Addition of two electrons incase of `Co^(2+)(d^(7))` destabilizes itmore . `Cr^(2+)(d^(4))` has one vacant subshell. `Fe^(2+)` gets more stabilizationas compared to `Cr^(2+)` through exchange energy . So, the correct order is`Mn gt Fe gt Cr gtCo`.
Promotional Banner

Topper's Solved these Questions

  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise COMPREHENSION 1|6 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise COMPREHENSION 2|6 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise VALUE BASED QUESTIONS|2 Videos
  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Important Questions|28 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|25 Videos

Similar Questions

Explore conceptually related problems

Which one of the following complexes? [Atomic numbers, Mn=25, Fe = 26, Co = 27, Ni = 28]

The pair having the same magnetic moment is [at. No. Cr = 24, Mn = 25, Fe = 26 " and " Co = 27]

Magnetic moment 2.83 BM is given by which of the following ions? "At. nos. Ti=22, Cr=24, Mn=25,Ni=28"

The complex ion which has no ""d"" electrons in the central atom is (at. Cr=24, Mn=25, Fe=26,Co=27)

Which one of the cyano complexes would exhibit the lowest value of para magnetic behaviour ? (At. No. Cr = 24, Mn = 25, Fe = 26, Co = 27)

PRADEEP-D- AND F-BLOCK ELEMENTS-COMPETITIONS FOCUS
  1. A transition metal ion exists in its highest oxidation state. It is ex...

    Text Solution

    |

  2. In context with the transition elements, which of the following statem...

    Text Solution

    |

  3. For the four successive transition elements (Cr, Mn, Fe, and Co), the ...

    Text Solution

    |

  4. The titanium (atomic number 22) compound that does not exist is

    Text Solution

    |

  5. Among TiF(6)^(2-), CoF(6)^(3-), Cu(2)Cl(2) and NiCl(4)^(2-) (At. No. T...

    Text Solution

    |

  6. The colour of light absorbed by an aqueous solution of CuSO(4) is

    Text Solution

    |

  7. The catalytic activity of transition metals and their compounds is mai...

    Text Solution

    |

  8. Among the following the compound that is both paramagnetic and coloure...

    Text Solution

    |

  9. The value of 'spin only' magnetic moment for one of the following conf...

    Text Solution

    |

  10. The correct statement about iron includes (I) the oxidation state of...

    Text Solution

    |

  11. Which one of the following does not correctly represent the correct or...

    Text Solution

    |

  12. Which of the following arrangements does not represent the correct ord...

    Text Solution

    |

  13. Which of the following statements about the interstitial compounds is ...

    Text Solution

    |

  14. Magnetic moments 2.84 B.M is given by : (At. nos. ni = 28, Ti = 22, ...

    Text Solution

    |

  15. Increasing basic properties of TiO(2), ZrO(2) and HfO(2) are in order ...

    Text Solution

    |

  16. Among the oxides, Mn(2)O(7)(I), V(2)O(3) (II), V(2)O(5) (III),CrO(IV) ...

    Text Solution

    |

  17. The acidic, basic or amphoric nature of Mn(2)O(7), V(2)O(5) and CrO ar...

    Text Solution

    |

  18. In chromite ore, the oxidation number of iron and chromium are respect...

    Text Solution

    |

  19. K(2)Cr(2)O(7) reacts with NH(4)Cl in presence of H(2)SO(4). The produc...

    Text Solution

    |

  20. When hydrogen peroxide is added to acidified potassium dichromate, a b...

    Text Solution

    |