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When sulphur dioxide is passed in an aci...

When sulphur dioxide is passed in an acidified `K_(2)Cr_(2)O_(7)` solution, the oxidation state of sulphur is changed from:

A

`+4` to `+6`

B

`+6` to `+4`

C

`+4` to 0

D

`+4` to `+2`

Text Solution

Verified by Experts

`ul(K_(2) Cr_(2)O_(7) +4H(2) SO_(4)rarr K_(2)SO_(4) + Cr_(2)(SO_(4))_(3) + 7H_(2)O+ 3(O))`
`SO_(2) + (O) + H_(2) O rarr H_(2) SO_(4) ] xx3`
`K_(2)Cr_(2)O_(7) + H_(2)SO_(4) + 3SO_(2) rarr K_(2)SO_(4) + Cr_(2)(SO_(4))_(3) + H_(2)O`
In `SO_(2)` , ox. state of `S= + 4 `. In `SO_(4)^(2-)`,ox.state of `S= +6`
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