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In which of the following ions, the colo...

In which of the following ions, the colour is not due to d-d transition?

A

`Ti(H_(2)O)_(6)^(3+)`

B

`CoF_(6)^(3+)`

C

`CrO_(4)^(2-)`

D

`[Cu(NH_(3))_(4)]^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
C

In `CrO_(4)^(2-)`, Cr is in `+6` oxidation state.It has `d^(0)` configuration .The coloure is dueto charge transfer and not due to d-d transition
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PRADEEP-D- AND F-BLOCK ELEMENTS-COMPETITIONS FOCUS
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  5. Which of the following does not give oxygen on heating ?

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  6. Identify the product and the colour when MnO(2) is fused with solid KO...

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  7. KMnO(4) can be prepared from K(2)MnO(4) as per the reaction 3MnO(4)^...

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  8. When a mananous salt is fused with a mixture of KNO(3) and and solid N...

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  9. In acidic medium MnO(4)^(2-)

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  10. The coloured spot ofKMnO(4) on any article can be bleached by

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  11. MnO(4)^(-) reacts with Br^(-) in alkaline pH to give

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  12. Amount of oxalic acid present in a solution can be determined by its t...

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  13. An explosion takes place when conc. H(2)SO(4) is added to KMnO(4) due ...

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  14. KMnO(4)gets reduced to

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  15. The colour of KMnO(4) is due to

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  16. In acidic medium, H(2)O(2) changes Cr(2)O(7)^(2-) to CrO(5) which has ...

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  17. The reaction of aqueous KMnO(4) with H(2)O(2) i acidic conditions give...

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  18. Name the gas that can readily decolourise acidified KMnO(4) solution:

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