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Consider the following statements: (...

Consider the following statements:
(I) La`(OH)_(3)` is the least basic among the hydroxides of Ianthanoids.
(II) `Zr^(4+)` and `Hf^(4+)` possess almost same ionic radii.
(III) `Cr^(4+)` can act as an oxidising agent .
which of the above statement is/ are true?

A

I and II

B

II and III

C

II only

D

I and II

Text Solution

Verified by Experts

`La(OH)_(3)` is most basic. Hence, (I) is wrong. (II) is correct due to lanthanoid contraction. (III) is correct because `Ce^(4+)` tends to change to stable `Cr^(3+)`
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Consider the following statement in respect of Lantinanoids : (i) The basic strength of hydroxides of lanthanoids increases from La (OH)_(3) to Lu (OH)_(3) . (ii) The lanthanoid ions Lu^(3+), Yb^(2+) and Ce^(4+) are diamagnetic. Which of the statements (s) given above is /are correct ?

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PRADEEP-D- AND F-BLOCK ELEMENTS-COMPETITIONS FOCUS
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  2. In context of the lanthanoids, which of the following statements is no...

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  3. Consider the following statements: (I) La(OH)(3) is the least b...

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  9. The reason for greater range of oxidation state in actinoids is attrib...

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  10. Reason of lanthanoid contraction is

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