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Which one of the following statements re...

Which one of the following statements related to lanthanons is incorrect ?

A

All the lanthanons are much more reactive than aluminium

B

`Ce(+4)` solutions are widely used as oxidizing agent in volumetric analysis

C

Europium shows `+2` oxidation state

D

The basicity decreases as the ionic radius decreases from Pr to Lu.

Text Solution

Verified by Experts

(a) Lnathnons are less reactive than aluminium due tohigh IP ( Lanthanoid contraction)
(b) `Ce^(+4)` is good oxidizing agent and easily converted into `Ce^(+3)`
(c ) Eu ( 63) `= 4f^(7) 5d^(0)6s^(2) ,Eu^(+2)= 4f^(7)`
(d) In lanthanoids series 'Ce' to 'Lu' ionic radius regularly decreases and covalent character increases and hence basic character of hydroxides decreses.
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