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[Fe(H(2)O)(5)NO]^(2+) is a complex forme...

`[Fe(H_(2)O)_(5)NO]^(2+)` is a complex formed during the brown ring test for `NO_(3)^(-)` ion. In this complex.

A

NO transfers its electron to `Fe^(2+)` so that we have iron as `Fe(I)` and NO as `NO_^(+)`

B

There are three unpaired electron so that its magnetic moment is 3.87 B.M.

C

The colour is due to charge transfer

D

All the above statements are correct.

Text Solution

Verified by Experts

`HgI_(2)overset(Delta)(rarr) Hg_ I_(2) ("violet vapours")`
`NO rarr NO^(+) + e^(-)`,
`{:(Fe^(2+) ,+,e^(-),rarr,Fe^(+)),((3d^(6)),,,,(3d^(7))),("4 unpaired "e^(-),,,,"3 unpaired "e^(-)):}`
`mu` for `Fe^(+) = sqrt(n(n+2))= sqrt(3 xx 5)` BM
`= sqrt(15) BM =3.87 BM`
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