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FOR NTH ORDER OF REACTION...

FOR NTH ORDER OF REACTION

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The order of reaction is an experimentally determined quanity. It may be zero, poistive, negative, or fractional. The kinetic equation of nth order reaction is k xx t = (1)/((n-1))[(1)/((a-x)^(n-1)) - (1)/(a^(n-1))] …(i) Half life of nth order reaction depends on the initial concentration according to the following relation: t_(1//2) prop (1)/(a^(n-1)) ...(ii) The unit of the rate constant varies with the order but general relation for the unit of nth order reaction is Units of k = [(1)/(Conc)]^(n-1) xx "Time"^(-1) ...(iii) The differential rate law for nth order reaction may be given as: (dx)/(dt) = k[A]^(n) ...(iv) where A denotes the reactant. For a reaction: I^(ɵ) + OCl^(ɵ) rarr IO^(ɵ) + Cl^(ɵ) in an aqueous medium, the rate of the reaction is given by (d[IO^(ɵ)])/(dt) = k([I^(ɵ)][OCl^(ɵ)])/([overset(ɵ)(OH)]) The overall order of the reaction is

The order of reaction is an experimentally determined quanity. It may be zero, poistive, negative, or fractional. The kinetic equation of nth order reaction is k xx t = (1)/((n-1))[(1)/((a-x)^(n-1)) - (1)/(a^(n-1))] …(i) Half life of nth order reaction depends on the initial concentration according to the following relation: t_(1//2) prop (1)/(a^(n-1)) ...(ii) The unit of the rate constant varies with the order but general relation for the unit of nth order reaction is Units of k = [(1)/(Conc)]^(n-1) xx "Time"^(-1) ...(iii) The differential rate law for nth order reaction may be given as: (dx)/(dt) = k[A]^(n) ...(iv) where A denotes the reactant. For a reaction: I^(ɵ) + OCl^(ɵ) rarr IO^(ɵ) + Cl^(ɵ) in an aqueous medium, the rate of the reaction is given by (d[IO^(ɵ)])/(dt) = k([I^(ɵ)][OCl^(ɵ)])/([overset(ɵ)(OH)]) The overall order of the reaction is

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