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Why a freshly prepared solution of FeSO4...

Why a freshly prepared solution of `FeSO_4` is used in Lassaigne's test for nitrogen ?

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Justify the following statements. i. Water mixed with formic acid cannot be separated by fractional distillation. ii. o -nitrophenol is steam volatile while p-nitrophenol is not. iii. Freshly prepared FeSO_4 solution is insisted during the test for nitrogen in Lassaignes test. iv. Copper spiral is used in the apparatus for Dumas method.