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In a reaction A to B the rate of react...

In a reaction ` A to B` the rate of reaction increases two times on increasing the concentration of the reactant four times, then order of reaction is

A

0

B

2

C

`1/2`

D

4

Text Solution

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The correct Answer is:
To determine the order of the reaction given that the rate of reaction increases two times when the concentration of the reactant is increased four times, we can follow these steps: ### Step-by-Step Solution: 1. **Define the Rate Law**: The rate of a reaction can be expressed as: \[ \text{Rate} = k [A]^n \] where \( k \) is the rate constant, \( [A] \) is the concentration of the reactant, and \( n \) is the order of the reaction. 2. **Set Up Initial Conditions**: Let the initial concentration of \( A \) be \( [A] \) and the initial rate be \( R_1 \): \[ R_1 = k [A]^n \] 3. **Set Up New Conditions**: When the concentration of \( A \) is increased to \( 4[A] \), the new rate \( R_2 \) is given as: \[ R_2 = k (4[A])^n \] According to the problem, \( R_2 = 2R_1 \). 4. **Substitute and Rearrange**: Substitute \( R_1 \) and \( R_2 \) into the equation: \[ 2R_1 = k (4[A])^n \] This gives us: \[ 2(k [A]^n) = k (4[A])^n \] 5. **Cancel Common Terms**: Since \( k \) and \( [A]^n \) are common on both sides, we can cancel them out (assuming \( k \neq 0 \) and \( [A] \neq 0 \)): \[ 2 = (4^n) \] 6. **Solve for \( n \)**: Now we need to solve for \( n \): \[ 2 = 4^n \] We can express \( 4 \) as \( 2^2 \): \[ 2 = (2^2)^n = 2^{2n} \] Therefore, we have: \[ 2 = 2^{2n} \] This implies: \[ 1 = 2n \quad \Rightarrow \quad n = \frac{1}{2} \] 7. **Conclusion**: The order of the reaction \( n \) is \( \frac{1}{2} \). ### Final Answer: The order of the reaction is \( \frac{1}{2} \). ---

To determine the order of the reaction given that the rate of reaction increases two times when the concentration of the reactant is increased four times, we can follow these steps: ### Step-by-Step Solution: 1. **Define the Rate Law**: The rate of a reaction can be expressed as: \[ \text{Rate} = k [A]^n ...
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-PRACTICE SET 01-PAPER 1 (PHYSICS & CHEMISTRY)
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