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Which of the following represents the co...

Which of the following represents the correct of the acidity in the given compounds ?

A

`FCH_(2)COOH gt CH_(3)COOH gt BrCH_(2)COOH gt CICH_(2)COOH`

B

`BrCH_(2)COOH lt CICH_(2)COOH lt FCH_(2)COOH lt CH_(3)COOH`

C

`FCH_(2)COOH gt CICH_(2)COOH gt BrCH_(2)COOH gt CH_(3) COOH`

D

`CH_(3)COOH lt BrCH_(2)COOH gt CICH_(2)COOH gt FCH_(2)COOH`

Text Solution

Verified by Experts

The correct Answer is:
C

Acidity decreases as the -I-effect of the group decreases. F is the most electronegative atom and hence, it has highest -I-effect among the halogens. Thus, the correct order is
` FCH_(2)COOH gt CICH_(2)COOH gt BrCH_(2) COOH gt CH_(3)COOH`
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