Home
Class 12
CHEMISTRY
Which N-atom of cyanide species is more ...

Which N-atom of cyanide species is more basic?

A

`CH_(3)-CN`

B

t-butyl cyanide

C

Ethyl cyanide

D

`NO_(2)-CH_(2)-CN`

Text Solution

Verified by Experts

The correct Answer is:
B
More electron density towards N-atom of -CN group moves, more localisation of negative charge occurs resulting more basic nature possessed by the species. Hence, (b0 is the right option.
Promotional Banner

Topper's Solved these Questions

  • PRACTICE SET 08

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise PAPER 2 OBJECTIVE TYPE|2 Videos

  • PRACTICE SET 10

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise PAPER 1 (PHYSICS & CHEMISTRY)|50 Videos

Similar Questions

Explore conceptually related problems

Which is more basic

is more basic than

Aniline is more basic than

(a) Which N of guanidine (I) is more basic and is more likely to be protonated ? (b) Why guanidine is the strongest organic N-base (K_(b) ~= 1) ? ( c) Why amides (III) are weakly basic (amphoteric), whereas phthalimide (IV) is an acid ?

Amines are more basic than

Amines are more basic than

Which among FeO and Fe_2O_3 is more basic?

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-PRACTICE SET 09-PAPER 1 (PHYSICS & CHEMISTRY)
  1. Carbon tetrachloride on hydrolysis with ethanolic KOH solution yields

    Text Solution

    |

  2. Cyclic trimer can be obtained as a polymerisation product by the carbo...

    Text Solution

    |

  3. Which N-atom of cyanide species is more basic?

    Text Solution

    |

  4. In SiF(6)^(2-) and SiCl(6)^(2-). which one exist?

    Text Solution

    |

  5. In the temperature changes from 27^(@)C to 127^(@)C, the relative perc...

    Text Solution

    |

  6. Dehydration of CH(3)-underset(OH)underset(|)(C)H-CH(2)-CH(3) is an aci...

    Text Solution

    |

  7. Manufacture of acetic acid by fermentation process is called

    Text Solution

    |

  8. The basicity of aniline is less than that of cyclohexylamine. This is ...

    Text Solution

    |

  9. Coupling of diazonium salts of following takes place in the order

    Text Solution

    |

  10. Proteins give white precipitate with Millon's regent, which is -

    Text Solution

    |

  11. For the purification of organic compounds, the latest technique follow...

    Text Solution

    |

  12. the ascending order of stability of the carbanion CH(3)(P),C(6)H(5)ove...

    Text Solution

    |

  13. Which of the following is a pseudohalide?

    Text Solution

    |

  14. pK(h) would be minimum for the salt

    Text Solution

    |

  15. Among the following, the compound that can be most readily sulphonated...

    Text Solution

    |

  16. Among the following sets of reactants which one produces anisole?

    Text Solution

    |

  17. How many geometrical isomers of the compound [Pt(NH(3))(Br)(Cl)(Py)] w...

    Text Solution

    |

  18. The product P formed in the following reaction sequence is Glucoseov...

    Text Solution

    |

  19. CH(3)COOH+PCl(5)to'P', choose the correct option from the following

    Text Solution

    |

  20. The plastic household crockery is prepared by using

    Text Solution

    |