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Dehydration of CH(3)-underset(OH)underse...

Dehydration of `CH_(3)-underset(OH)underset(|)(C)H-CH_(2)-CH_(3)` is an acid catalysed elimination reaction, this obeys

A

Saytzeff rule

B

Markownikoff's rule

C

Gibson rule

D

Hofmann rule

Text Solution

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The correct Answer is:
A

Saytzeff rule if alternate condition exist, H-atom eliminates from such carbon atom which has minimum number of hydrogen atoms.
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The IUPAC name of CH_(3)-underset(OH)underset(|)(CH)-CH_(2)-O-C_(2)H_(5) is:

CH_(3)-underset(OH)underset(|)CH-CH_(2)-underset(CH_(3))underset(|)CH-CHO

the compound which gives the most stable carbonium ion on dehydration (1). CH_(3)-underset(CH_(3))underset(|)(C)H-CH_(2)OH (2). CH_(3)underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-OH (3). CH_(3)CH_(2)CH_(2)CH_(2)OH (4). CH_(3)-underset(OH)underset(|)(C)H-CH_(2)CH_(3)

IUPAC name of CH_(3)-underset(OH)underset(|)(C)=underset(OH)underset(|)(C)-(CH_(3)) is

The IUPAC name of CH_(3)-underset(OH)underset(|)(CH)-CH=underset(CH_(3))underset(|)(C )-CHO is

CH_(3)-underset(CH_(3)) underset(|) (C)= CH_(2) underset("Peroxide") overset(HBr)to CH_(3)-underset(CH_(3)) underset(|) (CH)-CH_(2)Br reaction intermediate of this reaction is:

CH_(3)-CH_(2)-underset(OH)underset(|)(CH)-underset(CH_(3))underset(|)(CH)-CHO

The IUPAC name of CH_(3)-CH_(2)CH=underset(CH_(3))underset(|)"CC"H_(2)OH will be

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-PRACTICE SET 09-PAPER 1 (PHYSICS & CHEMISTRY)
  1. Which N-atom of cyanide species is more basic?

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  2. In SiF(6)^(2-) and SiCl(6)^(2-). which one exist?

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  3. In the temperature changes from 27^(@)C to 127^(@)C, the relative perc...

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  4. Dehydration of CH(3)-underset(OH)underset(|)(C)H-CH(2)-CH(3) is an aci...

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  5. Manufacture of acetic acid by fermentation process is called

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  6. The basicity of aniline is less than that of cyclohexylamine. This is ...

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  7. Coupling of diazonium salts of following takes place in the order

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  8. Proteins give white precipitate with Millon's regent, which is -

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  9. For the purification of organic compounds, the latest technique follow...

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  10. the ascending order of stability of the carbanion CH(3)(P),C(6)H(5)ove...

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  11. Which of the following is a pseudohalide?

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  12. pK(h) would be minimum for the salt

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  13. Among the following, the compound that can be most readily sulphonated...

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  14. Among the following sets of reactants which one produces anisole?

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  15. How many geometrical isomers of the compound [Pt(NH(3))(Br)(Cl)(Py)] w...

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  16. The product P formed in the following reaction sequence is Glucoseov...

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  17. CH(3)COOH+PCl(5)to'P', choose the correct option from the following

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  18. The plastic household crockery is prepared by using

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  19. Sodium benzoate is a commonly used foor preservative. It is

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  20. By wurtz reaction a mixture of methyl iodide and ethyl iodide gives

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