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If 111 mg of CaCl(2) and 12 mg of MgSO(4...

If 111 mg of `CaCl_(2)` and 12 mg of `MgSO_(4)` are present in 2L of water, what is its hardness (in gram `CaCO_(3)//p p m)` ?

A

5

B

10

C

15

D

203

Text Solution

Verified by Experts

The correct Answer is:
B

`underset(=111xx10^(3)mg)underset(40xx35xx2)(CaCl_(2))-= underset(=100xx10^(3)mg)underset(40+10+48)(CaCO_(3))`
`underset(=120xx10^(3)mg)underset(24+32+64)(MgSO_(4))-=underset(=100xx10^(3)mg)underset(40+12+40)(CaCO_(3))`
`111xx10^(3)mg` of
`CaCl_(2)=100xx10^(3)mg" of "CaCO_(3)`
11.1 mg of `CaCl_(2)`
`=(100xx10^(3)xx11.1)/(111xx10^(3))mg " of "CaCO_(3)`
`=10 mg " of "CaCO_(3)`
Similarly, `120xx10^(3)mg" of " MgSO_(4)`
`=100xx10^(3)mg " of " CaCO_(3)`
`12 mg " of " MgSO_(4)=(100xx10^(3))/(120xx10^(3))xx12mg" of "CaCO_(3)`
`=10mg" of "CaCO_(3)`
In 2 L of water, total weight of
`CaCO_(3) =10+10=20mg`
`therefore ` In 1 L of water, total weight of
`CaCO_(3)=(20)/(2)mg=10mg`
`therefore " In "10^(6)`mg of water, total weight of
`CaCO_(3)=10mg`
So, in `10^(6)` part water, hardness of water in terms of `CaCO_(3)=10`ppm
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One litre of a sample of hard water contains 1 mg of CaCl_(2) and 1 mg of MgCl_(2) . Find the total hardness of water in terms of parts of CaCO_(3) per 10^(6) parts of water by mass.

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A 50 mL sample of hard water containing Ca^(2+) and Mg^(2+) ions is titrated with 50 mL. 0.005 M EDTA solution at pH=10 , using eriochrome balck -T indicator to reach equivalence point. In a equal amount of hard water sample, Mg^(2+) ions are precipated as Mg(OH)_(2) by adding suitable amount of NaOH . the solution, after precipation of Mg(OH)_(2) , is strired and then titrated with EDTA solution using calcon as indicator, and it requires 10 mL of above EDTA solution to reach equivalence point. a. Calculate the strength of Ca^(2+) and Mg^(2+) ions present in hard water. b. Calculate the hardness due to Ca^(2+) ions in p p m of CaCO_(3) . c. Calculate the hardnesss due to Mg^(2+) ions in p p m of CaCO_(3) . d. Calculate the total hardness of water in p p m of CaCO_(3) .

0.012g of Ca(HCO_(3))_(2) is present in 500 ml of water. Presuming density of water to be 1g/cc, what is the hardness in ppm in terms of CaCO_(3) ?

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