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Which of the following has an optical is...

Which of the following has an optical isomer?
(en=ethylenediamine) ?

A

`[Zn(en)_(2)]^(2+)`

B

`[Zn(en)(NH_(3))_(2)]^(2+)`

C

`Co(en)_(3)]^(3+)`

D

`[CO(H_(2)O)_(4)(en)]^(3)`

Text Solution

Verified by Experts

The correct Answer is:
C

`[Ma_(2)b_(2)c_(2)]^(n pm),[Mabcdef]^(n pm)`,
`[M(A A)_(3)]^(n pm),[M(A A)_(2)a_(2)]^(n pm),`
`[M(A A)_(2)ab]^(n pm) and [M(AB)_(3)]^(n pm)`.
Thus, among the given options, only `[Co(en)_(3)]^(3+)` shows optical isomerism.
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