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The standard cell potential for the cell...

The standard cell potential for the cell `Zn|Zn^(2+) (1 M)|| Cu^(2+) (1 M)| Cu`
Given `E_(Cu^(2+)//Cu)^(@) = 0.34 V` and `E_(Zn^(2+)//Zn)^(@) = - 0.76 V` is

A

1.10 V

B

` - 0.42 V `

C

`-1.10 V`

D

None of these

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The correct Answer is:
To find the standard cell potential for the electrochemical cell `Zn|Zn^(2+) (1 M)|| Cu^(2+) (1 M)| Cu`, we can follow these steps: ### Step 1: Identify the half-reactions - The half-reaction for copper is: \[ Cu^{2+} + 2e^- \rightarrow Cu \quad (E^\circ = 0.34 \, V) \] - The half-reaction for zinc is: \[ Zn^{2+} + 2e^- \rightarrow Zn \quad (E^\circ = -0.76 \, V) \] ### Step 2: Determine the anode and cathode - The anode is where oxidation occurs, and the cathode is where reduction occurs. - Since zinc has a more negative standard reduction potential than copper, zinc will be oxidized (anode), and copper will be reduced (cathode). - Thus, we have: - Anode: \( Zn \rightarrow Zn^{2+} + 2e^- \) - Cathode: \( Cu^{2+} + 2e^- \rightarrow Cu \) ### Step 3: Write the standard cell potential formula The standard cell potential (E°cell) can be calculated using the formula: \[ E^\circ_{cell} = E^\circ_{cathode} - E^\circ_{anode} \] ### Step 4: Substitute the values Substituting the values we have: \[ E^\circ_{cell} = E^\circ_{Cu^{2+}/Cu} - E^\circ_{Zn^{2+}/Zn} \] \[ E^\circ_{cell} = 0.34 \, V - (-0.76 \, V) \] ### Step 5: Perform the calculation Calculating the above expression: \[ E^\circ_{cell} = 0.34 \, V + 0.76 \, V = 1.10 \, V \] ### Final Answer The standard cell potential for the cell `Zn|Zn^(2+) (1 M)|| Cu^(2+) (1 M)| Cu` is: \[ \boxed{1.10 \, V} \]
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