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Linkage isomerism....

Linkage isomerism.

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**Step-by-Step Text Solution:** 1. **Definition of Linkage Isomerism:** Linkage isomerism is a type of isomerism that occurs in coordination compounds. It refers to the phenomenon where two or more compounds have the same molecular formula but differ in the way the ligands are attached to the central metal atom. 2. **Understanding Ligands:** Ligands are ions or molecules that can donate a pair of electrons to the central metal atom to form a coordinate bond. The nature of the ligand and how it is attached to the metal can lead to different structural arrangements. ...
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The questions given below consist of Assertion (A) and Reason (R ) . Use the following key to select the correct answer. Assertion : Linkage isomerism arises in co-ordination complexes containing an ambident ligand. Reason : Ambidentate ligand has two donor atoms .

Statement-1: The complex [Cr(SCN)(NH_(3))_(5)]Cl_(2) is linkage isomeric with [Cr(NCS)(NH_(3))_(5)]Cl_(2) . Statement-2: SCN^(-) is an ambident ligand in which there are two possible coordination sites.

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The question consist of two statements each, printed as Assertion and Reason. While answering these questions you are required to choose any one of the following four responses: Assertion: The complex [Cr(SCN)(NH_3)_5]Cl_2 is linkage isomeric with [Cr(NCS)(NH_3)_5]Cl_2 . Reason: SCN^(-) is an ambident ligand in which there are two possible coordination sites.

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