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Cyclohexanol to cyclohexyl chloride...

Cyclohexanol to cyclohexyl chloride

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Cyclohexanol to cyclohexyl chloride :
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Identify the compound in the following pair that reacts with sodium iodide in acetone at a faster rate towards S_(N^(2)) mechanism. 1-Chlorohexane or cyclohexyl chloride:

How will you convert cyclohexanol to cyclohexanone?

Explain why (i) the dipole moment of chlorobenzene is lower than that of cyclohexyl chloride? (ii) alkyl halides, though polar, are immiscible with water? (iii) Grignard reagents should be prepared under anhydrous conditions?

Explain the following : (a) The dipole moment of chlorobenzone is lower than that of cyclohexyl chloride. (b) Alkyl halides, though polar, are immiscible with water. (c) Grignard reagents should be prepared under anhydrous condition.

Give reasons: (i). C-Cl bond length in chlorobenzene is shorter than C-Cl bond length in CH_(3)-Cl (ii). The dipole moment of chlorobenzene is less than of cyclohexyl chloride. (c). S_(N^(1)) reactions are are accompanied by racemisation is optically active alkyl halides.