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The packaging fration for a body centred...

The packaging fration for a body centred cubic structure is

A

0.42

B

0.53

C

0.68

D

0.82

Text Solution

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The correct Answer is:
To find the packing fraction for a body-centered cubic (BCC) structure, we can follow these steps: ### Step 1: Understand the Structure A body-centered cubic (BCC) structure consists of atoms located at each of the eight corners of a cube and one atom at the center of the cube. ### Step 2: Determine the Number of Atoms (Z) In a BCC unit cell, there are 2 atoms per unit cell. This is because each corner atom is shared among eight unit cells (1/8 of an atom from each corner) and the center atom is fully contained within the unit cell. Therefore: \[ Z = 2 \] ### Step 3: Calculate the Volume of Atoms in the Unit Cell The volume occupied by the atoms in the unit cell can be calculated using the formula for the volume of a sphere: \[ V_{\text{atom}} = \frac{4}{3} \pi r^3 \] For BCC, the effective radius of the atom can be derived from the relationship between the radius (r) and the edge length (a) of the cube. In a BCC structure: \[ a = \frac{4r}{\sqrt{3}} \] Thus, the volume of the two atoms in the unit cell is: \[ V_{\text{atoms}} = 2 \times \frac{4}{3} \pi r^3 = \frac{8}{3} \pi r^3 \] ### Step 4: Calculate the Volume of the Unit Cell The volume of the unit cell (V_cell) is given by: \[ V_{\text{cell}} = a^3 \] Substituting for a: \[ V_{\text{cell}} = \left(\frac{4r}{\sqrt{3}}\right)^3 = \frac{64r^3}{3\sqrt{3}} \] ### Step 5: Calculate the Packing Fraction The packing fraction (PF) is defined as the ratio of the volume occupied by the atoms to the total volume of the unit cell: \[ PF = \frac{V_{\text{atoms}}}{V_{\text{cell}}} \] Substituting the volumes we calculated: \[ PF = \frac{\frac{8}{3} \pi r^3}{\frac{64r^3}{3\sqrt{3}}} \] This simplifies to: \[ PF = \frac{8 \pi \sqrt{3}}{64} = \frac{\pi \sqrt{3}}{8} \] ### Step 6: Calculate the Numerical Value Using the approximate value of \(\pi \approx 3.14\): \[ PF \approx \frac{3.14 \times 1.732}{8} \approx \frac{5.441}{8} \approx 0.68 \] ### Conclusion Thus, the packing fraction for a body-centered cubic structure is approximately **0.68**.
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