ANTI-MARKOVNIKOV'S RULE

INTEGRAL AS AN ANTI-DERIVATIVE

which alkene does not follow Anti-Markownikoff's addition rule

Free Radicals Addition || Kolbe Electrolysis || Anti MarkownikOFf Rule

The anti-Markovnikov's addition of HBr to alkenes in the presence of peroxides was rationalized by

In the presence of peroxide, hydrogen chloride and hydrogen iodide do not give anti-Markovnikov's addition to alkenes because:

Using Markovnikov's rule, correctly predict the principal product of the following reactions: (i) "But-1-ene"+HIrarr (ii) "Vinyl chloride"+HIrarr (iii) But-2-"ene"+HIrarr (iv) 2-"Methylbut-2-ene"+HIrarr (v) "Pent-2-ene"+HIrarr Strategy: Use Markovnikov's rule for unsymmetrical alkenes: Positive part of the addendum ( adding molecule, HI ) gets attached to that doubly bonded carbon atom which possesses more number of hydrogen atoms: