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Oxidative Cleavage...

Oxidative Cleavage

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An known alkene with formula C_(7)H_(12) on oxidation with hot alkaline KMnO_(4) yields only the following product CH_(3)-overset(O)overset(||)C-CH_(2)CH_(2)CH_(2)CH_(2)-overset(O)overset(||)C-OH What is the structure of this alkene? Strategy: C_(7)H_(12)underset((2)H_(3)O^(+))overset((1)KMnO_(4),H_(2)O,Ooverset(-)H)rarrCH_(3)overset(O)overset(||)C CH_(2)CH_(2)CH_(2)CH_(2)overset(O)overset(||)C-OH Since the oxidation cleavage leads to just one product which contains the same number of carbon atoms as the reactant, the unknown alkene must have a double bond contained in a ring. The oxidative cleavage of the double bond result in the opening of the ring. To create the ring, remove the - OH group and doubly bonded O's and finally join the carboxylic acid carbon with ketone carbon by a double bond.

Cleavage || Classification OF Cleavage || Determinate Cleavage || Indeterminate Cleavage || Complete or Holoblastic Cleavage Meroblastic Cleavage

Knowledge Check

  • Dtermination cleavage is found in

    A
    Coelenterates
    B
    Annelida
    C
    Nematodes
    D
    All the above.
  • Meroblastic cleavage is

    A
    Total
    B
    Spiral
    C
    Incomplete
    D
    Horizontal.
  • Which of the following will periodic cleavage ?

    A
    `MeOC-overset(OH)overset(|)CH-underset(OH)underset(|)CH-COOMe`
    B
    C
    `Me-underset(OH)underset(|)CH-underset(NH_(2))underset(|)CH-Me`
    D
    `Me-underset(OH)underset(|)CH-CH_(2)-OH`
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