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Sodium Hydroxide

Sodium Hydroxide

Sodium Hydroxide (NaOH) is a strong base and an inorganic compound. It's commonly known as caustic soda or lye. 

Sodium hydroxide, commonly known as caustic soda or lye, is a powerful and versatile inorganic compound with widespread applications across various industries. Sodium hydroxide structure contains sodium, oxygen and Hydrogen. This compound is represented by the chemical formula NaOH.

Sodium Hydroxide

In this article, we will discuss important properties of Sodium Hydroxide.

1.0Chemical and Physical Properties of Sodium Hydroxide 

Let's explore some crucial aspects of sodium hydroxide properties- 

  • Composition: Sodium hydroxide is an inorganic compound comprising sodium (Na), oxygen (O), and hydrogen (H).
  • Physical State: It's a white, solid Crystal like substance at room temperature and readily dissolves in water, creating a highly alkaline solution.
  • Alkalinity: As a strong base, it completely dissociates in water, yielding sodium ions (Na⁺) and hydroxide ions (OH⁻).
  • Caustic Nature: Sodium hydroxide is highly caustic and corrosive to organic matter and human tissue, necessitating careful handling and precautions during use.

2.0Application of Sodium Hydroxide

Let’s discuss some important applications of Sodium hydroxide and its uses.


Application of sodium hydroxide

  • Chemical Manufacturing: Sodium Hydroxide serves as a fundamental ingredient in the production of a variety of chemicals. Sodium hydroxide uses involve the manufacture of sodium salts, dyes, plastics, soaps, detergents, and various organic and inorganic compounds.


  • Pulp and Paper Industry: Sodium hydroxide is a crucial part of the pulping process in paper manufacturing. It's employed in breaking down lignin and separating cellulose fibers from wood, aiding in the production of paper and cardboard.


  • Textile Industry: In textile production, it's used in treatments to mercerize cotton fabrics, giving them a smoother texture and enhancing their dye uptake and strength.


  • Cleaning Products: Due to its strong alkalinity and ability to dissolve grease and oils, sodium hydroxide is a key ingredient in various household and industrial cleaning products. It's found in drain cleaners, oven cleaners, detergents, and degreasers.


  • Water Treatment: In water treatment processes, it's utilized for pH adjustment, neutralizing acidic water, and controlling acidity and alkalinity levels in municipal and industrial water systems.


  • Petroleum Industry: Sodium hydroxide plays a role in refining petroleum products, including in the production of gasoline, diesel, and various petrochemicals.


  • Food Processing: Sodium hydroxide uses also involved in food processing, particularly for purposes like curing foods, adjusting pH levels, and, in certain cases, cleaning food equipment.


  • Biodiesel Production: Sodium hydroxide is employed in the transesterification process used to produce biodiesel from vegetable oils or animal fats.


  • Aluminum Production: It's utilized in the production of aluminum, where it helps remove impurities from bauxite ore during the refining process.


  • Soap and Cosmetic Industry: Sodium hydroxide plays a crucial role in the saponification process, reacting with fats and oils to create soap. In cosmetics, it's used in certain formulations for pH adjustment.

3.0Sodium Hydroxide Chemical Formula And Methods of Preparation

Sodium hydroxide is an ionic compound consisting of sodium cations (Na+) and hydroxide anions (OH-), forming an ionic bond. Its chemical formula is NaOH.

Sodium hydroxide preparation can be done through various methods, primarily involving the chemical reaction of sodium-containing compounds with hydroxide ions. The most common industrial method involves the following process known as the chloralkali process:

  • Mercury Cell Process (This method is less commonly used for sodium hydroxide preparation due to environmental concerns):
    • Electrolysis: A concentrated solution of sodium chloride (brine) is electrolyzed using a mercury cell. The electrolysis of brine produces chlorine gas at the anode, sodium hydroxide solution (caustic soda) at the cathode, and hydrogen gas.
    • Formation of Sodium Hydroxide: At the cathode, sodium ions (Na⁺) accept electrons and react with water (H₂O) to form sodium hydroxide (NaOH) and hydrogen gas (H₂).
  • Membrane Cell Process:
    • Electrolysis: Brine is electrolyzed in a membrane cell. This process involves separating the anode and cathode compartments with a membrane that allows only sodium ions to pass through.
    • Formation of Sodium Hydroxide: Sodium ions migrate through the membrane to the cathode, where they combine with hydroxide ions formed from water to produce sodium hydroxide solution and hydrogen gas.
    • This is widely used for sodium hydroxide preparation.
  • Diaphragm Cell Process:
    • Electrolysis: Similar to the membrane cell process, brine is electrolyzed in cells divided by a permeable diaphragm that allows the migration of sodium ions while preventing the mixing of chlorine and hydroxide ions.
    • Formation of Sodium Hydroxide: Sodium ions from the brine reach the cathode compartment and combine with hydroxide ions formed by the reduction of water, resulting in the production of sodium hydroxide solution and hydrogen gas.
Frequently Asked Questions

Sodium hydroxide itself is not considered environmentally friendly due to its high alkalinity and potential for causing harm. Proper disposal and handling are necessary to prevent environmental damage.

Sodium hydroxide dissociates completely in water to form sodium ions (Na⁺) and hydroxide ions (OH⁻). This reaction generates a highly alkaline solution.

Yes, in very controlled and diluted forms, sodium hydroxide is used in food processing, such as in the curing of olives, making pretzels, and in the production of certain Asian foods like lutefisk. However, it must be handled with care and precision to ensure safety.

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