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Assertion : Anilinium choride is more ac...

Assertion : Anilinium choride is more acidic than ammonium chloride.
Reason : Anilinium ion is resonance-stabilised.

A

if both Assertion and Reason are true and reason is the correct explanation of the assertion.

B

if both assertion and reason are true but reason is not the correct expalanation of the assertion

C

if assertion is true, reason is false

D

both assertion and reason are false statements.

Text Solution

Verified by Experts

The correct Answer is:
c

`underset("anilinum ion stronger acid")(C_(6)H_(5)overset(+)(NH_(3))) to underset("anilne weaker conjugated base")(C_(6)H_(5)NH_(2))+H^(+)`
Aniline is wekar base than ammonium chloride. In `NH_(4)CI` or alphatic amines the non-bonding electron pair of N is localized and is fully available for coordination with a proton. on the other hand, in aniline or other aromatic amines, the non bonding electron pair is delocalised into benzene rings by resonance.

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