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Which of the following statements is//ar...

Which of the following statements is`//`are correct?

A

`PbO_(2)` reacts with `HCl` to evolve `Cl_(2)` gas.

B

`PbO_(2)` reacts with `HNO_(3)` to form `O_(2)` gas.

C

`Pb_(3)O_(4)` reacts with `HCl` to evolve `Cl_(2)` gas.

D

`Pb_(3)O_(4)` reacts with `HNO_(3)` to form `PbO_(2)`, but `O_(2)` is not liberated.

Text Solution

Verified by Experts

The correct Answer is:
A, B, C, D

`PbO_(2)` is poweful oxidising agent and liberates `O_(2)` with acid.
`PbO_(2)+4HClrarrPbCl_(2)+2H_(2)O+Cl_(2)`
b. `PbO_(2)+2HNO_(3)rarrPb(NO_(3))_(2)+H_(2)O+(1)/(2)O_(2)`
c. `Pb_(3)O_(4)+8HClrarr3PbCl_(2)+4H_(2)O+Cl_(2)`
d. `Pb_(3)O_(4)+4HNO_(3)rarrPb(NO_(3))_(2)+PbO_(2)+2H_(2)O`
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