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Consider a titration of potassium dichro...

Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using diphenylamine as indicator. The number of moles of Mohr's salt required per mole of dichromate is:

A

3

B

4

C

5

D

6

Text Solution

Verified by Experts

The correct Answer is:
D

The following redox change takes place:
`6e^(-)+Cr_(2)O_(7)^(2-)to2Cr^(3+)(n=6)`
`Fe^(2+)toFe^(3+)(n=1)` (from Mohr's salt)
`1 Eq-=1Eq`
`(1)/(6)mol=(1)/(1)mol`
`1 mol=6 mol` of Mohr's salt
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