Home
Class 11
CHEMISTRY
A 3.0g sample containing Fe(3)O(4),Fe(2)...

A `3.0g` sample containing `Fe_(3)O_(4),Fe_(2)O_(3)` and an inert impure substance is treated with excess of `KI` solution in presence of dilute `H_(2)SO_(4)`. The entire iron is converted to `Fe^(2+)` along with the liberation of iodine. The resulting solution is diluted to `100 mL`. A `20 mL` of dilute solution requires `11.0 mL` of `0.5M Na_(2)S_(2)O_(3)` solution to reduce the iodine present. `A` `50 mL` of the diluted solution, after complete extraction of iodine requires `12.80 mL` of `0.25M KMnO_(4)` solution in dilute `H_(2)SO_(4)` medium for the oxidation of `Fe^(2+)`. Calculate the percentage of `Fe_(2)O_(3)` and `Fe_(3)O_(4)` in the original sample.

Promotional Banner

Topper's Solved these Questions

  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Archives Integer|2 Videos
  • STATES OF MATTER

    CENGAGE CHEMISTRY|Exercise Exercises (Ture False)|25 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Archives (Subjective)|23 Videos
CENGAGE CHEMISTRY-STOICHIOMETRY-Archives Subjective
  1. n-butane is produced by the monobromination of ethane followed by Wurt...

    Text Solution

    |

  2. A mixture of H(2)C(2)O(4) and NaHC(2)O(4) weighing 2.02 g was dissolve...

    Text Solution

    |

  3. A solid mixture 5 g consists of lead nitrate and sodium nitrate was he...

    Text Solution

    |

  4. A solution of 0.2 g of a compound containing Cu^(2+) and C(2)O(4)^(2-)...

    Text Solution

    |

  5. A 1 g sample of Fe(2)O(3) solid of 55.2% purity is dissolved in acid a...

    Text Solution

    |

  6. A 2.0 g sample of a mixture containing sodium carbonate, sodium bicarb...

    Text Solution

    |

  7. 1 g sample of AgNO(3) is dissolved in 50 mL of water, It is titrated w...

    Text Solution

    |

  8. The composition of a sample of wustite is Fe(0.93)O(1.00). What percen...

    Text Solution

    |

  9. A is a binary compound of a univalent metal. When 1.422 g of A reacts ...

    Text Solution

    |

  10. A mixture of ethane (C(2)H(6)) and ethene (C(2)H(4)) occupies 40 L at ...

    Text Solution

    |

  11. A 5.0 mL of solution of H(2)O(2) liberates 0.508 g of iodine from acid...

    Text Solution

    |

  12. A 20 mL mixture of CO, CH4, and Helium (He) gases is exploded by an el...

    Text Solution

    |

  13. A 3.0g sample containing Fe(3)O(4),Fe(2)O(3) and an inert impure subst...

    Text Solution

    |

  14. To a 25 mL H(2)O(2) solution excess of an acidified solution of potass...

    Text Solution

    |

  15. An aqueous solution containing 0.10 g KIO(3) (formula weight=214.0) wa...

    Text Solution

    |

  16. Calculate the volume of 0.5 M H2SO4 required to dissolve 0.5 g of copp...

    Text Solution

    |

  17. A plant virus is found to consist of uniform cylindrical particle of 1...

    Text Solution

    |

  18. Hydrogen peroxide solution (20 mL) reacts quantitatively with a soluti...

    Text Solution

    |

  19. One gram of charcoal adsorbs 400 " mL of " 0.5 M acetic acid to form a...

    Text Solution

    |

  20. Around 20% surface sites have adsorbed N(2). On heating N(2) gas evolv...

    Text Solution

    |