Home
Class 11
CHEMISTRY
At room temperature, ammonia gas at 1 at...

At room temperature, ammonia gas at `1 atm` pressure and hydrogen chloride gas at `P atm` pressure are allowed to effuse through identical pin holes from opposite ends of a glass tube of `1 m` length and of uniform cross- section. Ammonium chloride is first formed at a distance of `60 cm` from the end through which `HCl` gas is sent in. What is the value of `P`?

Text Solution

Verified by Experts

According to graham's law of diffusion for gases at different pressure
`(r_(HCl))/(r_(NH_(3))=(P_(HCl))/(P_(NH_(3)))sqrt((M_(NH_(3)))/(M_(HCl)))=(60)/(40)=(P)/(1)sqrt((17)/(36.5))`
or `P_(HCl)=((60)/(40))xxsqrt((36.5)/(17))=1.5xx1.465=2.198atm`
Promotional Banner

Topper's Solved these Questions

  • STATES OF MATTER

    CENGAGE CHEMISTRY|Exercise Ex 5.4|32 Videos
  • STATES OF MATTER

    CENGAGE CHEMISTRY|Exercise Exercises (Fill In The Blanks)|25 Videos
  • STATES OF MATTER

    CENGAGE CHEMISTRY|Exercise Ex 5.2|16 Videos
  • SOME BASIC CONCEPTS AND MOLE CONCEPT

    CENGAGE CHEMISTRY|Exercise Archives Subjective|11 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

At room temperature, ammonia gas at 1 atm pressure and HCl gas at pressure P atm are allowed to effuse through idential pin holes from opposite ends of a glass tube of 1 meter length and of uniform area of cross-section. NH_(4)Cl is first formed at a distance of 60 cm from the end through which HCl gas was sent in. Calculate the value of P.

Through the two ends of a glass tube of length 200cm hydrogen chloride gas and ammonia are allowed to enter At what distance ammonium chloride will first appear ? .

Two gases NO and O_(2) were introduced at the two ends of a 1m long tube simultaneously ( tube of uniform cross-section) . At what distance from NO gas end , Brown fumes will be seen.

X and Y are two volatile liquids with molar weights of 10gmol^(-1) and 40gmol^(-1) respectively. Two cotton plugs, one soaked in X and the other soaked in Y , are simultaneously placed at the ends of a tube of length L=24 cm, as shown in the figure. The tube is filled with an inert gas at 1 atm pressure and a temperature of 300K . Vapours of X and Y react to form a product whichh is first observed at a distance d cm from the plug soaked in X . Take X and Y to have equal molecular diameters and assume ideal behaviour for the inert gas and two vapours. The value of d in cm (shown in figure), as estimated from Graham's law, is

16 mL of He gas effuses through a pin hole in 4 sec from a container having P_(He) equal to 1 atm. If same container is filled with CH_(4) having pressure 2 atm, how much volume (in mL) of CH_(4) will be leaked through same pin hole in 2 sec?

In the given figure, atmospheric pressure p_0 = 1 atm and mercury column length is 9 cm. Pressure p of the gas enclosed in the tube is

An ideal gas at pressure P and temperature T is enclosed in a vessel of volume V. Some gas leaks through a hole from the vessel and the pressure of the enclosed gas falls to P'. Assume that the temperature of the gas remains constant during the leakage. What is the number of moles of the gas that have leaked ?

CENGAGE CHEMISTRY-STATES OF MATTER-Ex 5.3
  1. 200 mL of hydrogen and 250 mL of nitrogen, each measured at 15^(@)C an...

    Text Solution

    |

  2. 400 mL of N(2) gas at 700 mm and 300 mL of H(2) gas at 800 mm are intr...

    Text Solution

    |

  3. Two vessels of capactie 1.5 L and 2.0 L containing hydrogen at 750 mm ...

    Text Solution

    |

  4. A diver uses noen- oxygen mixture containing 7.4 g oxygen and 167.5 g ...

    Text Solution

    |

  5. A sample of O(2) is collected over water at 22^(@)C and 748 torr pessu...

    Text Solution

    |

  6. A cylinder containing nitrogen gas and same liquid water at a temperat...

    Text Solution

    |

  7. A gaseous mixture containing 8g of O(2) and 227 mL of N(2) at STPis e...

    Text Solution

    |

  8. A flask of 1.5 L capacity contains 400 mg of O(2) and 60 mg of H(2) a...

    Text Solution

    |

  9. 50 g of dinotrogen (N(2)) and 2.0 g of helium are enclosed in a vessel...

    Text Solution

    |

  10. A gaseous mixture contains 5.6 g of carbon (II) oxide and rest carbon ...

    Text Solution

    |

  11. At room temperature, ammonia gas at 1 atm pressure and hydrogen chlori...

    Text Solution

    |

  12. The volumes of ozone and chlorine diffusing in the same time are 35 mL...

    Text Solution

    |

  13. Which will diffuse faster, ammonia of CO(2) ? What are their relative ...

    Text Solution

    |

  14. A 4 : 1 molar mixture of He and CH(4) is contained in a vessel at 20 b...

    Text Solution

    |

  15. 20 dm^(3) of SO(2) diffuse through a porous partition in 60 s. what vo...

    Text Solution

    |

  16. One mole of nitrogen gas at 0.8atm takes 38s to diffuse through a pinh...

    Text Solution

    |