Home
Class 11
CHEMISTRY
Given: i. H(g) +CI(g) rarr HCI(g) Delt...

Given:
i. `H(g) +CI(g) rarr HCI(g) DeltaH =- 431 kJ`
ii. `HCI(g) +aq rarr H^(o+)(aq) +CI^(Theta) (aq) DeltaH =- 75.1 kJ`
iii. `H(g) rarr H^(o+) (aq)+e^(-) DeltaH = 1317 kJ`
iv. `CI(g) +e^(-) rarr cI^(Theta)(g) DeltaH =- 354 kJ`
a. Calculate the enthalpy of hydration of `HCI`
`H^(o+)(g) +CI^(Theta)(g) +aq rarr H^(o+)(aq) +CI^(Theta)(aq)`
b. Calculate teh enthalpy of hydration of `CI^(Theta)` ions if enthalpy of hydration of `H^(o+)` is zero.

Text Solution

Verified by Experts

a. `H^(o+)(g) +CI^(Theta) (g) +aq rarr H^(o+)(aq) +CI^(Theta)(aq) DeltaH = ?`
`DeltaH = DeltaH_(1) +DeltaH_(2) - DeltaH_(3) - DeltaH_(4)`
`=- 431 - 75.1 - 1317 - (-354)`
`=- 1469.1 kJ`
b. `CI^(Theta)(g)+aq rarr CI^(Theta) (aq), DeltaH_(5) = ?`
`H^(o+) (g) +aq rarr H^(o+) (aq), DeltaH_(6) = 0`
Given:
`H^(o+)(g) +CI^(Theta)(g)+aq rarr H^(o+) (aq) +CI^(Theta) (aq)`
`DeltaH =- 1469.1 kJ`
`DeltaH = DeltaH_(5) +DeltaH_(6)`
`:. DeltaH_(5) = DeltaH - DeltaH_(6)`
`= - 1469.1 - 0 =- 1469.1 kJ`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Exercises (Linked Comprehension)|74 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Exercises (Multiple Correct)|50 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Ex 6.5|30 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

Given: NaCI(s) +aq rarr Na^(o+) (aq) +CI^(Theta) DeltaH = 3.9 kJ Na^(o+)(g) +CI^(Theta)(g) rarr NaCI(s) DeltaH =- 788 kJ CI^(Theta)(g)+aq rarr CI^(Theta)(aq) DeltaH =- 394.1 kJ Calculate the enthalpy of hydration of Na^(o+) ions.

i. H_(2)(g) +CI_(2)(g)rarr 2HCI(g),DeltaH =- x kJ ii. NaCI +H_(2)SO_(4) rarr NaHSO_(4) +HCI, DeltaH =- y kJ iii. 2H_(2)O +2CI_(2) rarr 4HCI +O_(2),DeltaH =- z kJ From the above equations, the value of DeltaH of HCI is

Given that : O(g) + e^(-) to O^(-)(g) DeltaH = -142 kJ "mol"^(-1) O(g) + 2e^(-) to O^(2-)(g) Delta H = + 712 kJ "mol"^(-1) what will be the DeltaH for the reaction: O^(-)(g) + e^(-) to O^(2-)(g)

If 2AI(s) +1(1)/(2) O_(2)(g) rarr AI_(2)O_(3)(s), DeltaH =- 1667.8 kJ H_(2)(g) +(1)/(2)O_(2)(g) rarr H_(2)O(l), DeltaH =- 285.9 kJ Calculate DeltaH for the reaction AI_(2)O_(3)(s) rarr 2AI(s) +1(1)/(2)O_(2)(g)

Given that: i. C(s) + O_(2)(g) rarr CO_(2)(g) , DeltaH =- 94.05 kcal ii. H_(2)(g) +(1)/(2) O_(2)(g) rarr H_(2)O(l), DeltaH =- 68.32 kcal iii. C_(2)H_(2)(g) +(5)/(2) O_(2)(g) rarr 2CO_(2)(g) +H_(2)O(l),DeltaH =- 310.62 kcal The heat of formation fo acetylene is

H_(2)(g)+I_(2) (s) rarr 2HI (g), DeltaH=51.9 KJ/mole H_(2)(g)+I_(2)(g) rarr 2 HI (g), DeltaH=-9.2 kJ/mole. the heat of reaction of I_(2)(s) rarr I_(2) (g)

CENGAGE CHEMISTRY-THERMODYNAMICS-Exercises (Subjective)
  1. The free enegry changes for the two reactions given below are a. SO(...

    Text Solution

    |

  2. Given that: i. C("graphite") +O(2)(g) rarr CO(2)(g), DeltaH =- 393.7...

    Text Solution

    |

  3. Given: i. H(g) +CI(g) rarr HCI(g) DeltaH =- 431 kJ ii. HCI(g) +aq ...

    Text Solution

    |

  4. Given: NaCI(s) +aq rarr Na^(o+) (aq) +CI^(Theta) DeltaH = 3.9 kJ N...

    Text Solution

    |

  5. What would be the heat released when:

    Text Solution

    |

  6. Enthalpy of neutralisation of acetic acid by NaOh is -50.6 kJ mol^(-1)...

    Text Solution

    |

  7. The polymerisation of ethylene to linear polyethylene is represented b...

    Text Solution

    |

  8. An athelete is given 100g of glucose (C(6)H(12)O(6)) of energy equival...

    Text Solution

    |

  9. How much hea is liberated when one mole of gaseous Na^(o+) combines wi...

    Text Solution

    |

  10. State a chamical reaction in which DeltaH and DeltaU are equal .

    Text Solution

    |

  11. Which of the following is an intensive property. Surface tension, mass...

    Text Solution

    |

  12. State the first law of thermodynamics.

    Text Solution

    |

  13. For the reactions, N(2)(g) +3H(2)(g) rarr 2NH(3)(g) predict, whether t...

    Text Solution

    |

  14. Which has larger absolute entropy per mole? a. H(2)O(l) at 298 K or ...

    Text Solution

    |

  15. The dissolution of ammonium chloride in water is an endothermic proces...

    Text Solution

    |

  16. Does an aqueous solution of Mg^(2+) ions have larger entropy before or...

    Text Solution

    |

  17. Predict the sign of DeltaG for the reaction at a very low temperature ...

    Text Solution

    |

  18. DeltaH and DeltaS are +ve. Under what conditions, process will be spon...

    Text Solution

    |

  19. What is the limitation of the first law of thermodynamics?

    Text Solution

    |

  20. Which of the following is an extensive property?

    Text Solution

    |