Home
Class 11
CHEMISTRY
If the enthalpy of combustion of diamond...

If the enthalpy of combustion of diamond and graphite are `-395.4 kJ mol^(-1)` and `-393.6 kJ mol^(-1)`, what is enthalpy change for the `C("graphite") rarr C("diamond")`?

Text Solution

Verified by Experts

`C("diamond") +O_(2)(g) rarr CO_(2)(g) DeltaH =- 395.4 kJ mol^(-1)………(i)`
`C("graphite") +O_(2)(g) rarr CO_(2)(g) DeltaH =- 393.6 kJ mol^(-1) …..(ii)`
`C("graphite") rarr C ("diamond")`
Subtracting equation (i) from equation (ii), we get
`C("graphite") rarr C("diamond")`
`DeltaH = -393.6 kJ -(-395.4 kJ)`
`DeltaH = +1.8 kJ mol^(-1)`.
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Exercises (Linked Comprehension)|74 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Exercises (Multiple Correct)|50 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Ex 6.5|30 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

The enthalpies of combustion of diamond and graphite are - 395.4 kJ and - 393.5 kJ respectively calculate the enthalpy of transformation from diamond to graphite.

If the enthalpy of combustion of C (graphite) is -393.3kJ mol^(-1) , then for producing 39.3kJ of heat the amount of carbon required is

The enthalpies of combustion of carbon and carbon monoxide are -390 kJ mol^(-1) and -278 kJ mol^(-1) respectively. The enthalpy of formation of carbon monoxide is

The enthalpies of combustion of C_(("graphite")) and C_(("diamond")) are -393.5 and -395.4kJ//mol respectively. The enthalpy of conversion of C_(("graphite")) to C_(("diamond")) in kJ/mol is:

The enthalpies of formation of CO and CO_(2) are -110.5 KJ mol^(-1) and -393.5 KJ mol^(-1) respectively. The enthalpy of combustion of carbon monoxide is

The enthalpy of combustion of methane, graphite and dihydrogen at 298 K are, -890.3 kJ mol^(-1) -393.5 kJ mol^(-1) , and -285.8 kJ mol^(-1) respectively. Enthapy of formation of CH_(4)(g) will be

CENGAGE CHEMISTRY-THERMODYNAMICS-Exercises (Subjective)
  1. The heat of combustion of H(2)(g) at constant pressure and 300k is -28...

    Text Solution

    |

  2. The standard absolute entropy of a substance, (S^(Theta)) is the entro...

    Text Solution

    |

  3. If the enthalpy of combustion of diamond and graphite are -395.4 kJ mo...

    Text Solution

    |

  4. For a spontaneous process, which of the following is always true?

    Text Solution

    |

  5. H(2)(g) +(1)/(2)O(2)(g) rarr H(2)O(g) DeltaH =- 242 kJ mol^(-1) Bond...

    Text Solution

    |

  6. Which one of the following has the same value as Delta(f)H^(Theta), CO...

    Text Solution

    |

  7. For which of the following processes is DeltaS negative?

    Text Solution

    |

  8. Predict DeltaH gt DeltaU or DeltaH lt DeltaU. a. C("graphite") +O(2)...

    Text Solution

    |

  9. What is significance of T DeltaS in DeltaG = DeltaH - T DeltaS?

    Text Solution

    |

  10. What is the physical significance of free enegry?

    Text Solution

    |

  11. How does T DeltaS determine the spontaneity of process?

    Text Solution

    |

  12. N(2)(g) +3H(2)(g) rarr 2NH(3): DeltaH =- 92 kJ is Haber's process for...

    Text Solution

    |

  13. The energy released in the neutralisation of H(2)SO(4) and KOH is 59.1...

    Text Solution

    |

  14. CH(4)(g) +2O(2)(g) rarr CO(2)(g) +2H(2)O(l), DeltaH =- 890 kJ what i...

    Text Solution

    |

  15. H(2)(g) +CI(2)(g) rarr 2HCI(g) +185 kJ. State whether this reaction is...

    Text Solution

    |

  16. The heat of neutralization of a strong acid by a strong base is a cons...

    Text Solution

    |

  17. Explain why heat of neutralisation of strong acid and weak base is les...

    Text Solution

    |

  18. Find the enthalpy of formation of hydrogen flouride on the basis of fo...

    Text Solution

    |

  19. Calculate DeltaH for the reaction H(2)(g)+1//2O(2)(g)toH(2)O(g) gi...

    Text Solution

    |

  20. Calculate the resonance enegry of NO(2) ( :O-N=O: ) The measured ent...

    Text Solution

    |