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Calculate DeltaH for the reaction H(2)...

Calculate `DeltaH` for the reaction
`H_(2)(g)+1//2O_(2)(g)toH_(2)O(g)`
given the bond energies of H-H and O=O bonds and O-H bond are 433 kJ `mol^(-1)`, 492 kJ `mol^(-1) and 464kJ" "mol^(-1)`.

Text Solution

Verified by Experts

`H_(2)(g) +(1)/(2)O_(2)(g) rarr H_(2)O(g)`
`Delta_(f)H = BE` of product `-BE` of reactant
`= (BE of H_(2) +(1)/(2)BE of O_(2)) - (2BE of O-H)`
`= 433 +(1)/(2) xx492 -2 xx 464`
`= 433 +246 - 928 =- 249 kJ`
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Using the bond enthalpy data, calculate DeltaH of the following reaction: 2Cl_(2)(g)+2H_(2)O(g)to4HCl(g)+O_(2)(g) given that, bond energies of Cl-Cl,H-Cl,O-H and O=O are 242.8, 431.8,464 and 442kJ" "mol^(-1) respectively.

Calculate the standard enthalpy change (in kJ "mol"^(-1) ) for the reaction H_(2)(g)+O_(2)(g)toH_(2)O_(2)(g) , given that bond enthalpy of H-H, O=O,O-H and O-O (in kJ "mol"^(-1) ) are respectively 438, 498, 464 and 138.

Bond energies can be obtained by using the following relation: DeltaH (reaction) = sum Bond energy of bonds, broken in the reactants -sum Bond energy fo bonds, formed in the products Bond enegry depends on three factors: a. Greater is the bond length, lesser is the bond enegry. b. Bond energy increases with the bond multiplicity. c. Bond enegry increases with electronegativity difference between the bonding atoms. Use the bond enegries to estimate DeltaH for this reaction: H_(2)(g) +O_(2)(g) rarr H_(2)O_(2)(g) {:("Bond","Bond energy"),(H-H,436 kJ mol^(-1)),(O-O,142 kJ mol^(-1)),(O=O, 499kJ mol^(-1)),(H-O,460kJ mol^(-1)):}

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