Home
Class 11
CHEMISTRY
Find DeltaH of the following reaction: ...

Find `DeltaH` of the following reaction:
`OF_(2)(g) +H_(2)O(g) rarr O_(2)(g)+2HF (g)`, average bond energies of `O -F, O-H, O =O`, and `H - F` are `44,111, 118`, and `135 kcal mol^(-1)`, respectively.

Text Solution

Verified by Experts

`OF_(2)(g) +H_(2)O(g) rarr O_(2)(g) +2HF(g), DeltaH = ?`
`BE` of reactant `=2(O-F) +2(O-H)`
`= 2 xx 44 +2 xx 11 = 310 kcal`
`BE` of products
`O = O +2 (H-F)`
`= 118 +2 xx 135 = 388 kcal, DeltaH = H_(P) - H_(R)`
`DeltaH = 310 - 388 =- 78 kcal`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Exercises (Linked Comprehension)|74 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Exercises (Multiple Correct)|50 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Ex 6.5|30 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

Find Delta H of the following reaction : OF_(2) (g) + H_(2)O(g) rarr O_(2)(g) + 2 HF (g) , average bond energies of, O – H, O = O, H – F , O – F, are 111, 118, 135 and 44 kcal/mol respectively

Find Delta_(r )H of the reaction : OF_(2)(g)+H_(2)O(g)rarr O_(2)(g)+2HF(g) , Average bond energies of O-F, O-H, O=O, H-F are 44, 111, 118 and 270 kcal/mol respectively.

Calculate the enthalpy change (DeltaH) in KJ mol^(-1) , of the follwing reaction 2C_(2)H_(2)(g)+50_(2) (g)rarr4CO_(2)(g)+2H_(2)O(g) givin average bond enthalpies of various bonds i.e., C-H,C=C,O=O,O-H as 414,814,499,724 and 640 kJ mol^(-1) respectively. Express magnitude only.

Calculate the standard enegry change for the reaction: OF_(2)(g) +H_(2)O(g) rarr O_(2)(g) +2HF(g) at 298K The standard enthalpies of formation of OF_(2)(g), H_(2)O(g) , and HF(g) are +20, -250 , and -270 kJ mol^(-1) , respectively.

Calculate the enthalpy change (Delta H) of the following reaction 2C_(2)H_(2)(g)+5O_(2)(g)rarr4CO_(2)(g)+2H_(2)O(g) given average bond enthalpies of various bonds, i.e., C-H,C-=C,O=O,C=O,O-H as 414,814,499,724 and 640 kJ mol^(-1) respectively.

DeltaH for the reaction, OF_(2)+H_(2)OrarrO_(2)+2HF (B.E. of O-F, O-H, H-F and O=O are 44, 111, 135 and "119 kcal mol"^(-1) respectively)

Calculate heat of the following reaction at constant pressure, F_(2)O(g)+H_(2)O(g)rarrO_(2)(g)+2HF(g) The heats of formation of F_(2)O(g),H_(2)O(g) and HF(g) are 5.5 kcal-57kcal and -64 kcal repectively.

CENGAGE CHEMISTRY-THERMODYNAMICS-Exercises (Subjective)
  1. Calculate the resonance enegry of NO(2) ( :O-N=O: ) The measured ent...

    Text Solution

    |

  2. Boiling point of an organic compound is 310K. Its enthalpy of vaporisa...

    Text Solution

    |

  3. Predict whether the following reaction is possible or not at 300k. 2...

    Text Solution

    |

  4. Calculate the standard free energy change for the reaction: H(2)(g)...

    Text Solution

    |

  5. Calculate the entropy change for the following reaction H(2)(g) +CI(...

    Text Solution

    |

  6. Heat of neutralisation between HCI and NaOH is 13.7kcal and between HC...

    Text Solution

    |

  7. Find the heat of formation of ethyl alcohol for following data C(s) ...

    Text Solution

    |

  8. Enthalpy of neutralisation of acetic acid by NaOH is -50.6 kJ mol^(-1)...

    Text Solution

    |

  9. The enthalpies of combustion of carbon and carbon monoxide in excess o...

    Text Solution

    |

  10. Calculate the DeltaH^(Theta) for the reduction of Fe(2)O(3)(s) by AI(s...

    Text Solution

    |

  11. Find DeltaH of the following reaction: OF(2)(g) +H(2)O(g) rarr O(2)(...

    Text Solution

    |

  12. The heat of formation of ethane is -19.46 kcal. Bond enegries of H-H, ...

    Text Solution

    |

  13. Find the electron affinity of chlorine from the following data. Enthal...

    Text Solution

    |

  14. When 10g of AI is used for reduction in each of the following alumino ...

    Text Solution

    |

  15. The heat of combustion at constant volume at 27^(@)C of benzene and ac...

    Text Solution

    |

  16. Calculate Delta(f)H^(Theta) ICI(g) from the data DeltaH dissociatio...

    Text Solution

    |

  17. Calculate heat of dissociation for acetic acid from the following data...

    Text Solution

    |

  18. Delta(f)H^(Theta) per mole of NH(3)(g). NO(g), and H(2)O(l) are -11.04...

    Text Solution

    |

  19. From the following data, calculate the standard enthalpy of formation ...

    Text Solution

    |

  20. CsOH +HCI rarr CsCI +H(2)O, DeltaH =- 13.4 kcal mol^(-1)……….(i) CsOH...

    Text Solution

    |