Home
Class 11
CHEMISTRY
CsOH +HCI rarr CsCI +H(2)O, DeltaH =- 13...

`CsOH +HCI rarr CsCI +H_(2)O, DeltaH =- 13.4 kcal mol^(-1)……….(i)`
`CsOH +HF rarr CsF +H_(2)O, DeltaH =- 16.4 kcal mol^(-1) ………(ii)`
Calculate `DeltaH` for the ionisation of `HF` in `H_(2)O`.

Text Solution

Verified by Experts

`HF rarr H^(o+) +F^(Theta) DeltaH = ?`
From equation (i), we get
`CsOH +HcI rarr CsCI +H_(2)O`
or
`overset(Theta)OH (Strong base) +H^(o+)(acid) rarr H_(2)O DeltaH_(2) =- 13.4 kcal`
From equation (ii), we get
`overset(Theta)OH (Strong base) +HF (Weak acid) rarr H_(2)O DeltaH_(2) =- 16.4 kcal`
`DeltaH = DeltaH_(2) - DeltaH_(1)`
`=- 16.4 -(-13.4) == 3.0 kcal`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Exercises (Linked Comprehension)|74 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Exercises (Multiple Correct)|50 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Ex 6.5|30 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Archives Subjective|33 Videos

Similar Questions

Explore conceptually related problems

Calculate heat of dissociation for acetic acid from the following data: CH_(3)COOH +NaOH rarr CH_(3)COONa +H_(2)O DeltaH = - 13.2 kcal H^(o+) +overset(Theta)Ohrarr H_(2)O, DeltaH =- 13.7 kcal Also calculate heat of dissociation for NH_(4)OH if HCI +NH_(4)OH rarr NH_(4)CI +H_(2)O, DeltaH =- 12.27 kcal

HCI +NaOH rarr naCI +H_(2)O, DeltaH =- 57.1 kJ mol^(-1) DeltaH is the heat of ……………….of HCI and NaOH solution.

Calculate the enthalpy of formation of sucrose (C_11H_22O_11) from the following data: (i) C_(12)H_(22)O_(11) + 12O_(2) rarr 12CO_(2) + 11 H_(2)O, DeltaH = -5200.7 kJ mol^(-1) (ii) C + O_(2) rarr CO_(2), DeltaH = -394.5 kJ mol^(-1) (iii) H_(2) + 1/2 O_(2) rarr H_(2)O, DeltaH = H_(2)O, DeltaH = -285.8 kJ mol^(-1) .

If 2AI(s) +1(1)/(2) O_(2)(g) rarr AI_(2)O_(3)(s), DeltaH =- 1667.8 kJ H_(2)(g) +(1)/(2)O_(2)(g) rarr H_(2)O(l), DeltaH =- 285.9 kJ Calculate DeltaH for the reaction AI_(2)O_(3)(s) rarr 2AI(s) +1(1)/(2)O_(2)(g)

If H_(2)S+3/2 O_(2) rarr H_(2)O+SO_(2) , DeltaH=-136.7 Kcal H_(2)+1/2 O_(2) rarr H_(2)O, DeltaH=-68.4 Kcal S+O_(2) rarr SO_(2), DeltaH=-71 Kcal What is DeltaH_(f) of H_(2)S

Calculate the enthalpy of vaporisation for water form the following: H_(2)(g) +1//2O_(2)(g) rarr H_(2)O(g),DeltaH =- 57.0 kcal H_(2)(g) +1//2O_(2)(g) rarr H_(2)O(l),DeltaH =- 68.3 kcal Also calculate the heat required to change 1g H_(2)O(l) to H_(2)O(g)

C_(2)H_(2) + 5/2 O_2(2) rarr 2CO_(2) + H_(2)O , Delta H = -310 kcal C + O_(2) rarr CO_(2) , " "Delta H = -94 kcal H_(2) + 1/2 O_(2) rarr H_(2)O, " " Delta H = -68 kcal On the basis of the above equations, DeltaH_(f) (enthalpy of formation) of C_2H_2 will be :

{:(C+O_(2)(g)rarrCO_(2)" ......(i),",DeltaH=-"393 k J mol"^(-1)),(H_(2)+1//2O_(2)rarr H_(2)O", .....(ii)",DeltaH=-"287.3 k J mole"^(-1)),(2CO_(2)+2H_(2)O rarr C_(2)H_(5)OH+2O_(2)" .....(iii)",DeltaH="1366.8 kJ mol"^(-1)):} Find the standard enthalpy of formation of C_(2)H_(5)OH(l)

CENGAGE CHEMISTRY-THERMODYNAMICS-Exercises (Subjective)
  1. Calculate the resonance enegry of NO(2) ( :O-N=O: ) The measured ent...

    Text Solution

    |

  2. Boiling point of an organic compound is 310K. Its enthalpy of vaporisa...

    Text Solution

    |

  3. Predict whether the following reaction is possible or not at 300k. 2...

    Text Solution

    |

  4. Calculate the standard free energy change for the reaction: H(2)(g)...

    Text Solution

    |

  5. Calculate the entropy change for the following reaction H(2)(g) +CI(...

    Text Solution

    |

  6. Heat of neutralisation between HCI and NaOH is 13.7kcal and between HC...

    Text Solution

    |

  7. Find the heat of formation of ethyl alcohol for following data C(s) ...

    Text Solution

    |

  8. Enthalpy of neutralisation of acetic acid by NaOH is -50.6 kJ mol^(-1)...

    Text Solution

    |

  9. The enthalpies of combustion of carbon and carbon monoxide in excess o...

    Text Solution

    |

  10. Calculate the DeltaH^(Theta) for the reduction of Fe(2)O(3)(s) by AI(s...

    Text Solution

    |

  11. Find DeltaH of the following reaction: OF(2)(g) +H(2)O(g) rarr O(2)(...

    Text Solution

    |

  12. The heat of formation of ethane is -19.46 kcal. Bond enegries of H-H, ...

    Text Solution

    |

  13. Find the electron affinity of chlorine from the following data. Enthal...

    Text Solution

    |

  14. When 10g of AI is used for reduction in each of the following alumino ...

    Text Solution

    |

  15. The heat of combustion at constant volume at 27^(@)C of benzene and ac...

    Text Solution

    |

  16. Calculate Delta(f)H^(Theta) ICI(g) from the data DeltaH dissociatio...

    Text Solution

    |

  17. Calculate heat of dissociation for acetic acid from the following data...

    Text Solution

    |

  18. Delta(f)H^(Theta) per mole of NH(3)(g). NO(g), and H(2)O(l) are -11.04...

    Text Solution

    |

  19. From the following data, calculate the standard enthalpy of formation ...

    Text Solution

    |

  20. CsOH +HCI rarr CsCI +H(2)O, DeltaH =- 13.4 kcal mol^(-1)……….(i) CsOH...

    Text Solution

    |