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The enthalpy of formation of hypothetica...

The enthalpy of formation of hypothetical `MgCI` is `-125kJ mol^(-1)` and for `MgCI_(2)` is `-642 kJ mol^(-1)`. What is the enthalpy of the disproportionation of `MgCI`.

A

`392 kJ mol^(-1)`

B

`-392 kJ mol^(-1)`

C

`-767 kJ mol^(-1)`

D

`-517 kJ mol^(-1)`

Text Solution

Verified by Experts

`{:(i.,Mg(s)+CI_(2)(g)rarrMgCI_(2)(s),,DeltaH_(1)=-642),(ii.,Mg(s)+(1)/(2)CI(g)rarrMgCI(s),,DeltaH_(2)=-125),(iii.,2MgCIrarrMgCI_(2)+Mg,,DeltaH =?):}`
`DeltaH = DeltaH_(1) - 2DeltaH_(2)`
`=- 642 -2 xx 2 xx (-125) =- 392 kJ mol^(-1)`
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