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Heat of reaction at constant pressure is...

Heat of reaction at constant pressure is………….. .

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Heat of a reaction (Q) at constant pressure is equal to

Chemical reactions are invariably associated with the transfter of energy either in the form of heat or light. In the laboratory, heat changes in physical and chemical processes are measured with an instrument called calorimeter. Heat change in the process is calculated as {:(q = ms DeltaT,,s =Specific heat),(=cDeltaT,,c =Heat capacity):} Heat of reaction at constant volume is measured using bomb calorimeter. q_(V) = DeltaU = Internal energy change Heat of reaction at constant pressure is measured using simple or water calorimeter. q_(p) = DeltaH q_(p) = q_(V) +P DeltaV DeltaH = DeltaU +DeltanRT For which reaction will DeltaH = DeltaU ? Assume each reaction is carried out in an open container.

Chemical reactions are invariably associated with the transfter of energy either in the form of heat or light. In the laboratory, heat changes in physical and chemical processes are measured with an instrument called calorimeter. Heat change in the process is calculated as {:(q = ms DeltaT,,s ="Specific heat"),(=cDeltaT,,c ="Heat capacity"):} Heat of reaction at constant volume is measured using bomb calorimeter. q_(V) = DeltaU = Internal energy change Heat of reaction at constant pressure is measured using simple or water calorimeter. q_(p) = DeltaH q_(p) = q_(V) +P DeltaV DeltaH = DeltaU +DeltanRT The heat capacity of a bomb calorimeter is 500 JK^(-1) . When 0.1g of methane was burnt in this calorimeter, the temperature rose by 2^(@)C . The value of DeltaU per mole will be

CENGAGE CHEMISTRY-THERMODYNAMICS-Exercises (Fill In The Blanks)
  1. H(2)O(s) rarr H(2)O(l), DeltaH = 6.01 kJ DeltaH is the heat of ……………...

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  2. H(2)O(l) rarr H(2)O(s), DeltaH =- 6.01 kJ DeltaH is the heat of …………...

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  3. H(2)O(l) rarr H(2)O(g), DeltaH = +40.7 kJ DeltaH is the heat of …………...

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  4. H(2)O(g) rarr H(2)O(l), DeltaH =- 40.7 kJ DeltaH is the heat of……………...

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  5. When heat is absorbed by the ststem, the sign of the value of q is tak...

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  6. A system is……………..if it cannot exchange matter and energy with the sur...

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  7. The entropy of gases is always……………….than that of liquids.

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  8. Heat of reaction at constant pressure is………….. .

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  9. A bomb calorimeter is used to measure the value of……………….at constant……...

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  10. Delta^(Theta)G(standard free energy change) is free energy change for ...

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  11. H(2)(g)+Br(2)(g) rarr 2HBr(g), DeltaH^(Theta) =-72.40 kJ DeltaG^(The...

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  12. If DeltaS is ………………..the reaction does not proceed in the forward dire...

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  13. For the process, mormal egg rarr hard boiled egg, the sign of DeltaS i...

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  14. In………………..process, no heat is exchanged between the system and the sur...

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  15. In the combustion of CO, DeltaH is……………than DeltaU.

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  16. Gibbs-Helmholtz equation is………….. .

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  17. At equilibrium, the entropy change is………………. .

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  18. In an isothermal process,………………….remains constant.

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  19. A stable compound has……………………….heat of formation.

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  20. All combustion reactions are………………. .

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