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Any buffer solution can be used as a buf...

Any buffer solution can be used as a buffer upto two `pH` units only.

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A given acid may be used for preparing buffer soln, having `pH` value in the range of `pK_(a) +- 1`. In other words, any buffer can be used as buffer upto two `pH` units only, depending on the value of `pK_(a)`or `pK_(b)`. Since the limit of `pH` values is given by `pH = pK_(a) +- 1`, the best buffer will have `pH = pK_(a)`. For example, the best buffer of acetic acid `(pK_(a)` and `4.8)`, with sod acetate will be when acetic acid and sod. acetate are present in equivalent amounts. Thus in such cases,
`pH = pK_(a) = 4.8`
pH limits `= pK_(a) +- 1 = 3.8 to 5.8`
pH units `= 5.8 - 3.8 = 2`
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