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Out of the following acid base-reactions...

Out of the following acid base-reactions, reaction (b) and (c) are possible.
a. `PH_(3) + overset(o+)NH_(4) rarr overset(o+)PH_(4) +NH_(3)`
b. `NH_(3) + Poverset(o+)H_(4) rarr Noverset(o+)H_(4) + PH_(3)`
c. `(CH_(3))_(3) P + overset(o+)NH_(4) rarr (CH_(3))_(3) overset(o+)PH + NH_(3)`
d. `(CH_(3))_(3) N + PH_(4)^(o+) rarr (CH_(3))_(2) overset(o+)NH + PH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
A
Proton affinity of `NH_(3)`is greater than `PH_(3)`. Proton affinity `(CH_(3))_(3)P` is grater than `NH_(3)`.
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