Home
Class 11
CHEMISTRY
Find the value of Delta(f) H^(@) for the...

Find the value of `Delta_(f) H^(@)` for the reaction
`N_(2) O_(4) (g) + 3 CO(g) rarr N_(2) O (g) + 3 CO_(2) (g)`
Standard enthalpies of formation of `CO(g), CO_(2) (g), N_(2) O (g)`, and `N_(2) O_(4) (g)` are `- 110, - 393, 81`, and `9.7 kJ mol^(-1)`, respectively.
Strategy : The standard enthalpy change of a reaction is equal to the sum of the standard molar enthalpie of formation of the products each multiplied by its stiochiometric coefficient in the balanced equation, minus the corresponding sum of the standard molar enthalpies of formation of the reactants

Text Solution

Verified by Experts

`Delta_(r )H=SigmaDelta_(f)H("Products")-SigmaDelta_(f)H("Reactants")`
`=[Delta_(f)H(N_(2)O)+3Delta_(f)H(CO_(2))]-[Delta_(f)H(N_(2)O_(4))+3Delta_(f)H(CO)]`
`=[81+3(-393)]-[9.7+3(-110)] kJ=-777.7 kJ`
Promotional Banner

Topper's Solved these Questions

  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY|Exercise Chemical Equilibrium|72 Videos
  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY|Exercise Atomic Structure|94 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY|Exercise Assertion-Reasoning Type|1 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Analytical and Descriptive|6 Videos

Similar Questions

Explore conceptually related problems

Enthalpies of formation of CO(g), CO_(2)(g),N_(2)O(g) and N_(2)O_(4)(g) are -110, -393, 81 and 9.7 kJ mol^(-1) respectively. Calculate Delta_(r)H for the reaction: N_(2)O_(4)(g) + 3CO(g) to N_(2)O(g) + 3CO_(2)(g) .

Enthalpies of formation of CO(g), CO_(2)(g),N_(2)O(g) and N_(2)O_(4)(g) are -110, -393, 81 and 9.7 kJ mol^(-1) respectively. Calculate Delta_(r)H for the reaction: N_(2)O_(4)(g) + 3CO(g) to N_(2)O(g) + 3CO_(2)(g) .

Calculate the standard enegry change for the reaction: OF_(2)(g) +H_(2)O(g) rarr O_(2)(g) +2HF(g) at 298K The standard enthalpies of formation of OF_(2)(g), H_(2)O(g) , and HF(g) are +20, -250 , and -270 kJ mol^(-1) , respectively.

The enthalpy of formation of CO(g), CO_(2)(g),N_(2)O(g) and N_(2)O_(4)(g) is -110,-393,+81 and 10 kJ / mol respectively. For the reaction N_(2)O_(4)(g)+3CO(g)rarr N_(2)O(g)+3CO_(2)(g). Delta H_(r ) is

Calculate the enthalpy change for the reaction CH_(4)(g) + 2O_(2)(g) to CO_(2)(g) + 2H_(2)O(l) The enethalpy of formation of CH_(4)(g),CO_(2)(g) and H_(2)O(l) are -74.8 kJ mol^(-1) , -393.5 kJ mol^(-1) and -285.8 kJ mol^(-1) respectively.

Delta H_(1)^(@) for CO_(2)(g) , CO(g) and H_(2)O(g) are -393.5,-110.5 and -241.8 kJ mol^(-1) respectively. Standard enthalpy change for the reacion CO_(2)(g)+H_(2)(g) rarr CO(g) + H_(2)O(g) is

CENGAGE CHEMISTRY-NCERT BASED EXERCISE-Thermodynamics
  1. The enthalpy change on freezing of 1 mol of water at 5^(@)C to ice at...

    Text Solution

    |

  2. Enthalpy of combustion of carbon to CO(2) is -393.5 kJ mol^(-1). Calcu...

    Text Solution

    |

  3. Find the value of Delta(f) H^(@) for the reaction N(2) O(4) (g) + 3 ...

    Text Solution

    |

  4. Given N(2)(g)+3H(2)(g)=2NH(3)(g),DeltaH^(@)=-22 kcal. The standard e...

    Text Solution

    |

  5. Calculate the standard enthalpy of formation of CH(3)OH(l) from the fo...

    Text Solution

    |

  6. Calculate the enthalpy change for the process C Cl(4)(g) rarr C(g)+4...

    Text Solution

    |

  7. For an isolated system, DeltaU=0. What will be the value of DeltaS?

    Text Solution

    |

  8. For the reaction at 298 K 2A+B rarr C DeltaH=400 kJ mol^(-1) and D...

    Text Solution

    |

  9. For the reaction 2Cl(g) rarr Cl(2)(g), what are the signs of DeltaH ...

    Text Solution

    |

  10. For the reaction, 2A(g)+B(g) rarr 2D(g) DeltaU^(Θ)=-10.5 kJ and De...

    Text Solution

    |

  11. The equilibrium constant for a reaction is 10. What will be the value ...

    Text Solution

    |

  12. Comment on the thermodynamic stability of NO(g), given 1/2N(2)(g)+1/...

    Text Solution

    |

  13. Calculate the entropy change in surroundings when 1.00 mol of H(2)O(l)...

    Text Solution

    |

  14. 0.562g of graphite kept in a bomb calorimeter in excess of oxygen at 2...

    Text Solution

    |

  15. Red phosphorus reacts with liquid bromine in an exotermic reaction : 2...

    Text Solution

    |

  16. A swimmer coming out from a pool is covered with a film of water weig...

    Text Solution

    |

  17. With the help of thermochemical equations given below, determine Delta...

    Text Solution

    |

  18. The combustion of 1 mol of benzene takes place at 298 K and 1 atm. Aft...

    Text Solution

    |

  19. Use the bond enthalpies listed below to estimate the enthalpy change f...

    Text Solution

    |

  20. Explain the following terms: (a) System, surroundings (b) State fu...

    Text Solution

    |