Home
Class 11
CHEMISTRY
Propane has the structutre H(3)C-CH(2)-C...

Propane has the structutre `H_(3)C-CH_(2)-CH_(3)`. Use the average the bond enthalpies to estimate the change in the enthalpy, `Delta H`, for the following reaction:
`C_(3)H_(8)(g)+5O_(2)(g) rarr 3Co_(2)(g) + 4H_(2)O(g)`

Text Solution

Verified by Experts

Given `B.E.` of `C-C=347 kJ mol^(-1)`
`BE` of `C-H=414 kJ mol^(-1)`
`BE` of `O=OrArr498 kJ mol^(-1)`
`BE` of `C=OrArr741 kJ mol^(-1)`
`BE` of `O-HrArr464 kJ mol^(-1)`
Structure of propane: `CH_(3)-CH_(2)-CH_(3)`
`C_(3)H_(8)(g)+5O_(2)rarr 3CO_(2)(g)+4H_(2)O(g)`
`DeltaH=Sigma BE` of Reactants `-Sigma BE` of Products
`=[(2 BE` of `C-C+8 BE of C-H)+5 BE` of `O=O]-[6 BE` of `C=O+8 BE` of `O-H]`
`=(2xx347+8xx414+5xx498]-(6xx741+8xx464]`
`=(694+3312+2490)-(4446+3712)`
`=6496-8158`
`=-1662 kJ mol^(-1)`
`=- 1.662xx10^(3) kJ mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY|Exercise Chemical Equilibrium|72 Videos
  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY|Exercise Atomic Structure|94 Videos
  • ISOMERISM

    CENGAGE CHEMISTRY|Exercise Assertion-Reasoning Type|1 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Analytical and Descriptive|6 Videos

Similar Questions

Explore conceptually related problems

At 298K , the enthalpy of combustion of CH_(4) corresponds to the reaction CH_(4)(g) +2O_(2)(g) rarr CO_(2)(g)+2H_(2)O(g)

The enthalpy change for the reaction, C_(2)H_(4)(g)+3O_(2)(g)to2CO_(2)(g)+2H_(2)(g) is called:

Using bond enthalpies (symbolized by epsilon ) an estimated value of DeltaH^(@) for the reaction H_(2)C=CH_(2)(g)+H_(2)(g)rarrCH_(3)-CH_(3)(g) would be

Predict the effect of compression on the following equilibrium reaction: CH_4(g) + H_2O(g) hArr CO(g) +3H_2(g)

CENGAGE CHEMISTRY-NCERT BASED EXERCISE-Thermodynamics
  1. In what way internal energy is different from enthalpu? Explain both t...

    Text Solution

    |

  2. Which of the following are open, close or nearly isolated system? (a...

    Text Solution

    |

  3. Which of the following rae state functions? (a) Height of a hill ...

    Text Solution

    |

  4. Give the appropriate reason for the followings: a. It is a preferabl...

    Text Solution

    |

  5. (a) Calculate the energy needed to raise the temperature of 10.0g of ...

    Text Solution

    |

  6. Standard vaporization enthalpy of benzene at its boiling point is 30.8...

    Text Solution

    |

  7. Use the standard enthalpies of formation and calculation the enthalpy ...

    Text Solution

    |

  8. Acetic acid ( ethanoic acid ) and hydrochloric acid react with KOH sol...

    Text Solution

    |

  9. Specific heat of Li(s),Na(s),K(s),Rb(s) and Cs(s) at 398K are 3.57,1.2...

    Text Solution

    |

  10. Calculate the enthalpy change when 2.38 g of carbon monoxide (CO) vapo...

    Text Solution

    |

  11. Propane has the structutre H(3)C-CH(2)-CH(3). Use the average the bond...

    Text Solution

    |

  12. If standard enthalpy change Delta(r )H^(Θ) + -2.05 xx 10^(3) kJ mol^(-...

    Text Solution

    |

  13. What is the basic difference between enthalpy of formation and enthalp...

    Text Solution

    |

  14. Use standard enthalpies of formation to calculate the value of Delta(r...

    Text Solution

    |

  15. Calculate the Delat(r )H^(Θ) for the reaction H-underset(Cl)underset...

    Text Solution

    |

  16. The enthalpy change (Delta H) for the reaction N(2) (g)+3H(2)(g) rar...

    Text Solution

    |

  17. A 1.250 g sample of octane (C(8)H(18)) is burned in excess of oxygen ...

    Text Solution

    |

  18. 20.0 g of ammonium nitrate (NH(4)NO(3)) is dissolved In 125 g of water...

    Text Solution

    |

  19. A chemist while studying the properties of gaseous C(2)Cl(2)F(2), a ch...

    Text Solution

    |

  20. Compounds with carbon-carbon double bond, such as ethylene, C(2)H(4), ...

    Text Solution

    |