Home
Class 12
CHEMISTRY
The standard potential of Cl^(c-)|AgCl|A...

The standard potential of `Cl^(c-)|AgCl|Ag` half cell is related to that of `Ag^(o+)|Ag` though the expression.
`E^(c-)._(Ag^(o+)|Ag)=E^(c-)._(Cl^(c-)|AgCl|A)+(RT)/(F)ln K_(sp)(AgCl)`

Text Solution

Verified by Experts

The correct Answer is:
F

The current expression is
`E^(c-)._(Cl^(c-)|AgCl|Ag)=E^(c-)._(Ag^(o+)|Ag)+(RT)/(F)ln K_(sp)(AgCl)`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY|Exercise Archieves (Linked Comprehension )|13 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY|Exercise Archieves Multiple Correct Ansers|2 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY|Exercise Exercisefill In The Blanks|25 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|29 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY|Exercise Archives (Subjective)|14 Videos

Similar Questions

Explore conceptually related problems

Match matrix (E_(Ag^(+)//Ag)^(@)=0.8K_(sp)(AgCl)=10^(-10))

What would be the electrode potential of a silver electrode dipped in a saturated solution of AgCl in contact with 0.1 M KCl solution at 25^(@)C ? E^(c-)._(Ag^(o+)|Ag)=0.799 V K_(sp) of AgCl=1xx10^(-10)

6.537 xx 10^(-2)f of metallic Zn was added to 100 mL of saturated solution of AgCl . Calculate log .([Zn^(2+)])/([Ag^(o+)]) . Given : E^(c-)._(Ag^(o+)|Ag)=0.80V, E^(c-)._(Zn^(2+)|Zn)=-0.763V . K_(sp) of AgCl~~10^(-10), atomic weight of Zn=65.37

Calculate the potential of silver electrode in a saturated solution of AgBr(K_(sp)=6xx10^(-13)) containing 0.1 M KB r . E^(c-)._(Ag^(o+)|Ag)=0.80V.

The standard electrode of a metal ion (Ag|Ag^(o+)) and metal - insoluble salt anion (Ag|AgCl|Cl^(c-)) are related as

The standard reduction potential of the Ag^(o+)|Ag electrode at 298K is 0.799V . Given that for AgI,K_(sp)=8.7xx10^(-17) , evaluate the potential of the Ag^(o+)|Ag electrode in a saturated solution of AgI . Also calculate the standard reduction potential of the I^(c-) |AgI|Ag electrode.

CENGAGE CHEMISTRY-ELECTROCHEMISTRY-Exercisetrue / False
  1. The absolute value of standard electrode protential can be determined ...

    Text Solution

    |

  2. Sodium cannot be obtained by the electrolysis of aqueous solution of N...

    Text Solution

    |

  3. The standard potential of Cl^(c-)|AgCl|Ag half cell is related to that...

    Text Solution

    |

  4. In a Daniell cell, electrons flow from zinc electrode to copper electr...

    Text Solution

    |

  5. Compounds of active metals (Zn, Na, Mg) are reducible by H(2) whereas ...

    Text Solution

    |

  6. The standard potential of hydrogen half cell is zero at all conditions...

    Text Solution

    |

  7. The conventional value of zero of the standard hydrogen half cell hold...

    Text Solution

    |

  8. The current - carrying ions in an electrolytic cell are not necessaril...

    Text Solution

    |

  9. Cations having more negative potential than -0.828V are reduced in pre...

    Text Solution

    |

  10. At the anode, the species having minimum reduction potential is formed...

    Text Solution

    |

  11. In a galvanic cell, the half cell with higher potential provides a red...

    Text Solution

    |

  12. In highly alkaline medium, the anodic process during the electrolytic ...

    Text Solution

    |

  13. Metallic anodes smore reactive than platinum tend to pass into the sol...

    Text Solution

    |

  14. The mass of a substance deposited on the cathode or anode during elect...

    Text Solution

    |

  15. The cell potential becomes half if the cell reaction is divided by 2 t...

    Text Solution

    |

  16. Rusting of Fe is quicker in saline water than in ordinary water.

    Text Solution

    |

  17. F(2) is prepared by the electrolysis of molten KHF(2) and anhydrous HF...

    Text Solution

    |

  18. In Hall's process for the preparation of Al, graphite anode has a long...

    Text Solution

    |

  19. In Down's process for the manufacture of sodium , CaCl(2), is added to...

    Text Solution

    |

  20. In Castner - Kellner cell for the manufacture of NaOH( caustic soda ),...

    Text Solution

    |